acids/bases Flashcards

1
Q

lewis acid

A

electron pair acceptor

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2
Q

lewis base

A

electron pair donor

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3
Q

strong acids

A

100% ionized (completely dissociated) in water

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4
Q

weak acids

A

only a small % ionized (incompletely dissociated) in water

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5
Q

if Keq is greater than 1, the reaction favors…

A

the product

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6
Q

if Keq is less than 1, the reaction favors…

A

the reactants

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7
Q

Le Chatelier’s Principle

A

if a chemical system in equilibrium is disturbed, the system will adjust to restore equilibrium

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8
Q

what two variables alter equilibrium?

A
  1. change in reactant/product concentration
  2. change in temperature
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9
Q

what does pH measure?

A

solution acidity

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10
Q

pH equation

A

= -log [H+]

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11
Q

pH of pure water

A

7

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12
Q

body pH

A

7.4

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13
Q

Henderson-Hasselbach equation

A

pH = pKa + log [conjugate base]/[acid]

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14
Q

how does a buffer solution resist changes in pH?

A

by adding small amounts of either acid or base

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15
Q

buffer solution constituents

A
  1. a weak acid or weak base
  2. the salt of a weak acid/base
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16
Q

is water a good buffer?

A

no, it is a poor buffer

17
Q

buffers at equilibrium

A

the pH will change minimally with the addition of H+ or OH-

18
Q

what biological buffers help regulate pH in the human body?

A

bicarbonate, phosphate, + protein

19
Q

homeostatic range for blood pH

A

7.35-7.45

20
Q

pH acidosis

A

pH less than 7.35

21
Q

pH alkalosis

A

pH greater than 7.45

22
Q

chemical buffer systems

A

equilibrium bases. quickest and least permanent response. temporarily “tie up” excess acids + bases

23
Q

what are the 3 main systems chemical buffer systems use?

A
  1. carbonic acid - bicarbonate
  2. phosphate
  3. protein
24
Q

respiratory mechanism

A

second to respond. removes CO2 + therefore H2CO3. respiratory center involved

25
Q

renal mechanism

A

slowest to respond + most permanent. takes hours to days. kidneys remove metabolic acids

26
Q
A
27
Q

what buffer system is important in ICF + urine?

A

phosphate

28
Q

what buffer system is important in the ECF?

A

carbonic acid - bicarbonate

29
Q

carbonic acid-bicarbonate buffer system

A

most significant buffering compound in blood

30
Q

what buffer system is important in ECF, ICF, + interacting with other buffer systems?

A

protein

31
Q

hemaglobin buffer

A

transports oxygen and acts as a pH buffer in the blood

32
Q

acidosis

A

excess addition of hydrogen ions to the body fluids. pH is decareased & H+ is increased

33
Q

alkalosis

A

excess removal of hydrogen ions from body fluids. pH is increased & H+ is decreased

34
Q

respiratory acidosis

A

CO2 increases, H+ increases, & pH decreases

35
Q

respiratory alkalosis

A

CO2 decreases, H+ decreases, & pH increases

36
Q

metabolic acidosis

A

H+ increases, pH decreases, CO2 increases

37
Q

metabolic acidosis compensation

A

exhaling more CO2

38
Q

metabolic alkalosis

A

H+ decreases, pH increases, CO2 decreases

39
Q

metabolic alkalosis compensation

A

exhaling less CO2