C9- Crude oil and fuels Flashcards

1
Q

Crude oil def?
How is it extracted?
Made of what?
Source of what?

A

A mixture made from remains of biomass from microscopic organisms (algae and plankton)
Drilling
Different hydrocarbons
Petrol and diesel fuel

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2
Q

How was crude oil made?

A

Layers of rock, creating high pressure and temperature, lack of oxygen

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3
Q

Hydrocarbon

A

A compound that contains only hydrogen and carbon atoms

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4
Q

How to make crude oil useful?

A

Fractional distillation to separate the substances

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5
Q

What are alkanes?
What mainly consists of alkanes?

A

Saturated hydrocarbons, contain maximum number of hydrogen atoms
Crude oil

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6
Q

What do straight lines in alkanes represent?
General formula for alkane molecules?

A

Single covalent bonds
CnH 2n+2

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7
Q

First 6 alkanes?

A

Methane
Ethane
Propane
Butane
Pentane
Hexane

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8
Q

Alkane state at room temp depends on..?
Why?

A

Depends on intermolecular forces
Bigger forces, higher boiling point

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9
Q

Smaller chains of hydrocarbons
Boiling point?
Volatility?
Viscosity?
Flammability?

A

Lower, weak intermolecular forces, need less energy to overcome
High volatility- turns into gas easily
Low viscosity, very runny
Highly flammable

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9
Q

Larger chains of hydrocarbons?
Boiling point?
Volatility?
Viscosity?
Flammability?

A

Higher, stronger intermolecular forces, more energy to overcome
Low volatility
High viscosity
Lower flammability

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10
Q

How is crude oil separated?
Into what and its def?

A

Fractional distillation
Fractions- groups which have similar boiling points

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11
Q

Describe the process of fractional distillation of crude oil

A

Crude oil heated at around 350 oc, fed into fractionating column as vapour, some is drawn off as a liquid at bottom
Vapours rise until they reach their boiling point, then cool and condense
These fractions collected as a liquid
Hydrocarbons with lowest boiling points move to top of column where coolest

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12
Q

What are the products of complete combustion of a hydrocarbon?
What does incomplete combustion of a hydrocarbon produce?

A

Carbon dioxide and water

Carbon monoxide

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13
Q

How to test the products of complete combustion of a hydrocarbon?

A

Gas produced from flame, travels through ice bath where the water turns blue cobalt chloride paper pink, and condenses due to ice.
Gas then bubbled through limewater, where carbon dioxide turns it cloudy

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14
Q

Complete combustion…
Oxygen?
More likely in?
H atoms become?
C atoms become?
Products cause?

A

Enough oxygen
Small alkanes and blue bunsen flame
Water
Carbon dioxide
Contributes to climate change

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15
Q

Incomplete combustion
Oxygen?
More likely in?
H atoms become?
C atoms become?
Products cause?

A

Not enough oxygen
Large alkanes and yellow bunsen flame
Water
Carbon monoxide or carbon (soot)
Carbon monoxide is toxic, carbon causes lung disease

16
Q

How to work out… in combustion of hydrocarbon equation?
CO2 atoms?
H2O atoms?
O2 atoms?

A

CO2= number of C atoms in hydrocarbon
H2O= CO2 +1
O2= CO2 + (1/2 x H2O)

17
Q

What is cracking?
What type of reaction is it?

A

Process of breaking down long hydrocarbons into shorter more useful ones like, alkanes and alkenes
Thermal decomposition

18
Q

General formula for alkenes?
How to tell alkenes?

A

CnH2n
Unsaturated, contains double bond between C atoms

19
Q

How to test for an unsaturated hydrocarbon?

A

Bromine solution will turn from orange to colourless

20
Q

Difference between thermal and catalytic cracking

A

Thermal- high temp and pressure
Catalytic- low temp and pressure

21
Q

Thermal cracking
Takes place in?
Temp?
Pressure?
Catalyst?

A

Industry
450-750oc
70 atm
None

22
Q

Catalytic cracking industry?
Temp?
Pressure?
Catalyst?

A

500oc
1atm
Zeolites

23
Q

Catalytic cracking laboratory?
Temp?
Pressure?
Catalyst?

A

Bunsen flame
1 atm
Broken crockery, pumice stone