C10- Organic reactions Flashcards

1
Q

Homologous series

A

Organic compounds in the same functional group, each member differs by CH2 e.g alkenes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Products of complete combustion of an alkene

A

Carbon dioxide and water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is more reactive, alkanes or alkenes?
Why?
Where do the reactant molecules go?

A

Alkenes due to their double C bond
Reacting molecules join to the alkene across the double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Hydrogenation of alkenes
Reactant?
Conditions?
Creates?
Example?

A

H2
150 oc, Ni catalyst
Saturated hydrocarbon (alkane)
C2 H4 + H2 —> C2 H6

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Halogenation of alkenes
Reactant?
Conditions?
Example?

A

I2, Br2, Cl2
Aqueous solution
C2 H4 + Br2 —> C2 H4 Br2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Hydration of alkenes
Reactant?
Conditions?
Creates?
Example?

A

H2O steam
High temp and pressure, catalyst
Alcohol
C2 H4 + H2O —> C2 H5 OH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Alcohols
Displayed formula is similar to ?
End in?

A

Alkane, remove H and add OH
-OH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Carboxylic acids
How to create the displayed formula?
End in?

A

Alkane, remove H and add a double bond to O and an OH
-COOH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Esters
How to create the displayed formula?
End in?

A

Replace the H in carboxylic with a hydrocarbon
-COO-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Products of
ethanol + ethanoic acid
methanol + propanoic acid

A

ethyl ethanoate
methyl propanoate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

3 Uses of alcohols

A

Ethanol in alcoholic drinks, solvents in perfumes, fuels

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Combustion of alcohols
Key fact?
Flame?
Products?

A

Flammable
Creates a blue flame
Carbon dioxide, water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Natural way alcohols are made?
Word equation?
Reactant?
Catalyst?
Ad and dis?

A

Fermentation
Glucose–> ethanol + carbon dioxide
Glucose from plants
Yeast
Low temp, takes longer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Industry way alcohols are made?
Word equation?
Reactant and from where?
Catalyst?
Ad and dis?

A

Hydration of ethenes
Ethene + steam–> ethanol
Ethene from crude oil
Phosphoric acid
Takes shorter, high temp

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Alcohol reaction with sodium
Forms?
Observations?
Methanol + sodium–>
Butanol + potassium–>

A

Forms hydrogen and salt
Fizzes, gets smaller
Sodium methoxide + hydrogen
Potassium butoxide + hydrogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Oxidation of ethanol
Reactants?
Products?

A

Ethanol + acidified potassium dichromate
Ethanoic acid + water

17
Q

2 key properties of carboxylic acids?
Carboxylic acid + metal carbonate forms? and observation?

A

Soluble in water, weak acids
Salt, water, carbon dioxide, fizzes

18
Q

Weak acid def?

A

An acid that partially ionises in solution to form H+ ions

19
Q

Formula equation for ethanoic acid in solution?
Carboxylic acid reacting with metal carbonate compared to HCl?

A

CH3COOH⇌ CH3COO- + H+
Carboxylic has higher pH, lower conc of H+ ions, slower reaction with metal carbonate than strong acids

20
Q

How to make esters equation
What are esters used for?

A

carboxylic acid + alcohol ⇌ ester + water
when using an acid catalyst
Perfumes and flavourings as they are fragrant