Biological Oxidation Flashcards

1
Q

Are redox reactions coupled

A

yes

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2
Q

What is a redox couple

A

.

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3
Q

The free energy change of a redox system is proportionate to what?

A

.

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4
Q

What is Redox Potential? How is it a comparable measure

A

.

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5
Q

What does a positive reduction potential mean

A

.

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6
Q

What is the purpose of the galvanic cell

A

.

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7
Q

How is redox potential a changeable measure

A

.

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8
Q

Equation of standard redox potential and when it is used

A

.

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9
Q

Equation of normal redox potential and when it is used

A

.

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10
Q

How do electrons flow in redox systems

A

.

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11
Q

Describe oxi-reductive reactions? How do you calculate standard Gibbs free energy

A

.

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12
Q

How are oxi-reductive reactions catalysed?

A

.

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13
Q

What substrates are normally oxidative?

A

.

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14
Q

What is the final acceptor of H atoms and e-?

A

.

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15
Q

What are the 3 types of Biological Oxidation reactions

A

.

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16
Q

Describe Dehydrogenation

A

.

17
Q

Describe Oxygenase reactions

A

.

18
Q

Describe oxygenation by e- transfer

A

.

19
Q

What are the 8 REDOX systems with biological importance

A

.

20
Q

Describe the NAD REDOX system -*

A

.

21
Q

Describe the Flavin REDOX system*

A

.

22
Q

Describe Cytochromes systems*

A

.

23
Q

Describe the Thiole REDOX system*

A

.

24
Q

What system is Glutathione in? What is its role?

A

.

25
Q

What system is Lipoic acid (lipoate) in? What is its role?

A

.

26
Q

What system is Thioreduxin in? What is its role?

A

.

27
Q

Describe the Quinone REDOX system*

A

.

28
Q

vE*

A

.

29
Q

Describe the Non-heme Fe-containing REDOX system

A

.

30
Q

Describe Ascorbic REDOX system*

A

.

31
Q

What are the 3 enzymes of redox processes

A

.

32
Q

Describe oxidase enzymes

A

.

33
Q

Describe DHs enzymes

A

.

34
Q

Describe Oxygenase enzymes

A

.

35
Q

Give example of a dioxygenase*

A

.

36
Q

Give example of a monodioxygenase*

A

.