Amount of substance Flashcards
What are the definitions of hydrated and anhydrous?
Hydrated = a crystalline compound that contains water molecules
Anhydrous = a substance that contains no water molecules
What is the definition of water of crystallisation?
Water molecules that form an essential part of the crystalline structure
How do you calculate no. moles of water of crystallisation in a hydrated salt?
anhydrous H2O
mass
moles
ratio 1 : x
How do you write a dot formula of hydrated salts?
E.g. MgCl2H10O5 = MgCl2.5H2O
Why is a hydrated salt heated multiple times?
If it is heated to a constant mass then you can ensure that all of the water of crystallisation has been removed
What is the definition of an empirical formula?
The simplest whole number ratio of atoms in a compound
What is the definition of a molecular formula?
The actual number of atoms of an element in a compound
How do you calculate empirical formula?
With the mass, moles, ratio, E.F table
e.g. Mg N
mass 72/24.3 28/14
How do you calculate molecular formula from an empirical formula?
- Find the multiplication factor (n) between empirical and molecular
- Multiply empirical by multiplication factor
n = Mr of molecular (given) / Mr of empirical (calculated)
How would not putting the lid back onto the crucible while cooling affect the no. moles of water of crystallisation?
More water molecules from the air would condense back into the crucible so the mass of water LOST would decrease
mass (water lost) –> less
moles –> less
x –> lower
What is the equation for percentage uncertainty?
% uncertainty = (no. readings x uncertainty of equipment / quantity) x 100
What is the formula for calculating no. particles?
particles = moles × NA (Avogadro’s constant)
What is the ideal gas equation?
pV = nRT
p = pressure, Pa V = volume, m3 n = moles R = 8.314 T = temperature, K
What are the unit conversions you need to know for the ideal gas equation?
kPa /1000 = Pa
cm3 / 1000000 = m3
dm3 / 1000 = m3
°C + 273 = K
What is the formula triangle which links moles, mass and Mr?
mass
moles Mr