3.3.12 - Polymerisation Flashcards
Formation of condensation polymers
Form when a water molecule is removed from the species of a reaction
Polyamides
Formed in a reaction between dicarboxylic acids and a diamine. A molecule of water is removed, leaving an amine linkage
Polyamide examples
Nylon-6,6,
Kevlar
Polyesters
Formed in a reaction between dicarboxylic acids and a diol, producing an ester linkage
Polyester example
Terylene
Polypeptides
Formed from multiple amino acids. A single monomer can produce a polymer due to the presence of both a -NH and -OH group
Hydrolysis
Condensation polymers can be broken down back into the constituent molecules by the addition of H2O. Water is attracted to the polar regions of the polymer meaning the links can be broken down
Condensation polymers bonding
Contain polar bonds. Hydrogen bonds and dipoles can also form between separate polymer chains
Condensation polymers uses
Bulletproof vests, heat protective materials
Breaking down of polyalkanes
Have to be broken down by burning which produces harmful products such as SO2 or CO2, which can lead to acid rain
Breaking down of polyesters and polyamides
Can be broken down through hydrolysis due to the polarity within the polymer molecules