3.1.3 - Bonding Flashcards
Ionic Bonding
Occurs between a metal and a non-metal. Electrons are transferred from the metal to the non-metal to achieve full outer shells. When electrons are transferred, it creates ions. Oppositely charged ions attract through electrostatic forces to form a giant ionic lattice
Common compound ions
Sulfate
Hydroxide
Nitrate
Carbonate
Ammonium
Covalent Bonding
Forms between two non-metals. Electrons are shared between the two outer shells to achieve a full outer shell. Multiple electron pairs can be shared to produce multiple covalent bonds
Dative Bonding
Dative or coordinate bonds form when both of the electrons in the shared pair are supplied from a single atom. Once a dative bond has formed, it is treated as a standard covalent bond
Metallic Bonding
Consists of a lattice of positively charged ions surrounded by a ‘sea’ of delocalised electrons. This produces a very strong electrostatic force of attraction between these oppositely charged particles
Ionic Crystal Structure
High melting and boiling point. The electrostatic forces holding the ionic lattice together are strong and require a lot of energy to overcome. When molten or in solution, ionic substances can conduct electricity. Ionic substances are often brittle materials
Metallic Crystal Structre
Often good conductors. Also malleable as the layers of positive ions are able to slide over one another. Have high melting points and are nearly always solid at room temperature.
Simple Molecular Crystal Structure
Consist of covalently bonded molecules held together with weak van der waals forces. These are very weak forces, so simple molecular substances have low melting and boiling points. Very poor conductors as they have no charged particles
Macromolecular Crystal Structure
These substances are covalently bonded into a giant lattice structure. Each atom has multiple covalent bonds which are very strong, giving it a very high melting point. Macromolecular substances are rigid.
Linear
2 bonding pairs and a bond angle of 180
Bent
2 bonding pairs, 2 lone pairs and a bond angle of 104.5
Trigonal planar
3 bonding pairs and a bond angle of 120
Triangular pyramid
3 bonding pairs, 1 lone pair and a bond angle of 107
Tetrahedral
4 bonding pairs and a bond angle of 109.5
Trigonal bipyramid
5 bonding pairs and bond angles of 90 and 120