3.2.4 - Period 3 Elements Flashcards
Equation for reaction between sodium and water
2Na + 2H2O –> 2NaOH + H2
Equation for reaction between magnesium and water
Mg + 2H2O –> Mg(OH)2 + H2
Sodium and Magnesium reactivity
Sodium is more reactive than magnesium as it only has to lose one electron to form an ion whereas magnesium has to lose two.
Magnesium and steam
Steam can be used to increase the speed of reaction. Steam provides the reaction with greater energy resulting in a violent reaction
Flame colour of magnesium when reacting with steam
bright white
Equation for reaction between magnesium and steam
Mg + H2O –> MgO + H2
Period 3 elements reacting with oxygen
Form oxides with each element in their highest oxidation state. This number is often the same as the group number
Oxide of sodium and oxygen
Sodium oxide (Na2O), +1 oxidation state
Oxide of magnesium and oxygen
magnesium oxide (MgO), +2 oxidation state
Oxide of aluminium and oxygen
Aluminium oxide (Al2O3), +3 oxidation state
Oxide of silicon and oxygen
Silicon dioxide (SiO2), +4 oxidation state
Oxide of phosphorus and oxygen
Phosphorus oxide (P4O10), +5 oxidation state
Oxide of sulfur and oxygen
Sulfur dioxide (SO2), +4 oxidation state (Can react to form SO3 with +6 oxidation state but requires high temp and catalyst)
Structure & Bonding of Na2O
Ionic
Relative melting point of Na2O
1250°c
Reactivity of Na2O
Vigorous
Structure & Bonding of MgO
Ionic
Relative melting point of MgO
2750°c
Reactivity of MgO
Vigorous
Structure & Bonding of Al2O3
Ionic (Covalent Character)
Relative melting point of Al2O3
2000°c
Reactivity of Al2O3
Slow but faster if powdered
Structure & Bonding of SiO2
Macromolecular
Relative melting point of SiO2
1500°c
Reactivity of SiO2
Slow
Structure & Bonding of P4O10
Simple covalent
Relative melting point of P4O10
500°c
Reactivity of P4O10
Vigorous
Structure & Bonding of SO2
Simple covalent
Relative melting point of SO2
-10°C
Reactivity of SO2
Burns steadily
Ionic oxides reaction with water
Form alkaline solutions with a pH around 10-14
Equation for reaction between Na2O and water
Na2O + H2O –> 2NaOH
Equation for reaction between MgO and water
MgO + H2O –> Mg(OH)2
Simple covalent oxides reaction with water
Form acidic solutions with a pH around 0-2 and when in solution these acids dissociate into H+ ions and ions of conjugate bases
Equation for reaction between P4O10 and water
P4O10 + 6H2O –> 4H3PO4
Equation for reaction between SO2 and water
SO2 + H2O –> H2SO3
Equation for reaction between SO3 and water
SO3 + H2O –> H2SO4
Reaction between basic, ionic oxides and acids
Produces a salt and water which is a neutralisation reaction
Equation for reaction between Na2O and HCl
Na2O + 2HCl –> 2NaCl + H2O
Equation for reaction between MgO and H2SO4
MgO + H2SO4 –> MgSO4 + H2O
Reaction between acidic, covalent oxides and bases
Produces a salt and water in a neutralisation reaction
Equation for reaction between SiO2 and NaOH
SiO2 + 2NaOH –> Na2SiO3 + H2O
Equation for reaction between P4O10 and NaOH
P4O10 + 12NaOH –> 4Na3PO4 + 6H2O
Equation for reaction between SO2 and NaOH
SO2 + 2NaOH –> Na2SO3 + H2O
Equation for reaction between SO3 and NaOH
SO3 + 2NaOH –> Na2SO4 + H2O
Bonding in aluminum oxide
Partially ionic and covalent meaning it is insoluble in water as the ions don’t dissociate
Aluminium oxide can act as both an…
acid and base meaning it is amphoteric.
Aluminium oxide can react to form…
a salt and water in neutralisation reactions
Equation for reaction between Al2O3 and H2SO4
Al2O3 + 3H2SO4 –> Al2(SO4)3 + 3H2O
Equation for reaction between Al2O3, NaOH and water
Al2O3 + 2NaOH + 3H2O –> 2NaAl(OH)4