3.3.1- Intro To Organic Chemistry Flashcards
Definition of empirical formula
The simplest whole number ratio of atoms of each element in a compound
Definition of molecular formula
Shows actual number of atoms of each element in a compound
Definition of general formula
The number of atoms of each element in a substance which has n carbon atoms. All the molecules in a homologous series have general formula
Definition of structural formula
How the atoms are joined in a molecule
Define displayed formula
Shows all atoms and all bonds in a molecule
Define skeletal formula
Uses lines to represent bonds each point represents a carbon atom, H atoms and bonds to H atoms are not shown only if they are part of a functional group
Characteristics of homologous series
- A series of compounds of similar structure each member differs by a relating unit
- share general formula
- contain same functional group
- similar chemical properties
- gradual change in p. Properties
- prepared in similar methods
Define functional group
The atoms or group of atoms that is responsible for most of the chemical reactions of a molecule
What is a trival name ?
Based on some property or historical aspects
Systematic names meaning
Based on agreed set of rules (IUPAC) exact structure can be found from name
Systematic name
Stem
Suffix
Stem - number of carbon atoms in longest chain bearing the functional group and a prefix showing the position and identity of any side chains
Suffix - an ending that tells you which functional group is present
Alkanes name for each carbon atoms
Meth -1 Eth - 2 Prop - 3 But- 4 Pent - 5. Hex- 6 Hept- 7 Oct - 8 Non- 9 Dec-10
General rule for nomenclature for the stem
Look for longest chain
Carbon atoms must be in a continuous row
Uses prefixes
General rule for nomenclature side chains
Named before chain name
Prefix -yl to basic stem
Lowest number on side chain
General rule for nomenclature for more than 1 side chain
- alphabetical order
- Lowest numbers
- Each chain given own number
- identical chain prefix with di,Teri, tetra
- number separated from name by ‘-‘
- number separated from number by ‘,’