3.1.9-Rate Equations Flashcards

1
Q

What is the rate equation showing

A

It shows the relationship between concentration of reactants to the rate of chemical reaction

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2
Q

Define order of reaction

A

With respect to a reactant is the power to which the concentration of a reactant is raised

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3
Q

Define overall order of reaction

A

The sum of the powers of the concentration terms in the rate equation

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4
Q

Define rate constant

A

The constant of proportionality in a rate equation, value of which is dependent on temperature and activation energy in a reaction

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5
Q

What is the only thing K is affected by

A

Temperature

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6
Q

What does the Arrhenius equation show

A

The relationship between temperature and the rate constant

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7
Q

Show 3 forms of the Arrhenius equation

A

K= Ae^ -Ea/RT

LnK= LnA - Ea/RT

Ea = RT(LnA-LnK)

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8
Q

Draw graph to represent Arrhenius equation and label

A

Draw

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9
Q

Describe what the Arrhenius graph is showing

A

Natural log of Arrhenius equation gives a straight line means activation energy and Arrhenius constant can be found from graph

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10
Q

How is the rate equation determined

A

Experimentally determines relationship

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11
Q

What can rate equations tell us

A

Tell us about mechanism and if there is a catalyst

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12
Q

Draw the zero order concentration time graph

A

Draw

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13
Q

Draw the first order concentration time graph

A

Draw

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14
Q

Draw the second order concentration time graph

A

Draw

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15
Q

How can you find the rate constant from the concentration time graph

A

On the zero order graph only the gradient gives the the rate constant

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16
Q

Draw zero order rate concentration graphs

A

Draw

17
Q

What does a horizontal line mean on a rate concentration graph

A

Zero order

18
Q

Draw rate concentration graph of first order

A

Draw

19
Q

What does a rising straight line mean on a rate concentration graph

A

First order

20
Q

Draw second order concentration time graph

A

Draw

21
Q

What does a upward curve mean on a rate concentration graph

A

Second order

22
Q

What methods are used to make a rate concentration graphs

A

Intial rates method

Continuous rates method

23
Q

Explain initials rates method

A

Doing several experiments where the the initial rate is measured and initial concentrations reagent is changed

24
Q

Explain continuous rates method

A

Doing one experiment where rate and concentration of a reagent is measured at several times during reaction

25
Q

What is the rate determining step

A

Overall a reaction is dependent on its slowest step which is called the rate determining step