24.5 redox and qualitative analysis Flashcards
colour of MnO4-
purple
colour change in reaction of Fe2+ and MnO4-
purple to colourless
how is Fe2+ oxidised to Fe3+
react with MnO4- ions
reaction of Fe2+ and MnO4 -
colour of Mn2+
colourless
colour of Fe3+
orange-brown
colour of Fe2+
pale green
how is Fe3+ reduced to Fe2+
react with I-
reaction of Fe3+ and I-
colour change in reaction of Fe3+ and I-
orange-brown to brown
colour of Cr2O7 2-
orange
colour of Cr3+
green
colour of Cr2+
pale blue
how is Cr2O7 2- reduced to Cr3+
react with Zn
reaction of Cr2O7 2- and Zn
colour change in reaction of Cr2O7 2- and Zn
orange to green
how is Cr3+ reduced to Cr2+
add excess zinc
reaction of Cr3+ and excess zinc
colour change in reaction of Cr3+ and excess Zn
green to pale blue
how is Cr3+ oxidised to CrO4 2-?
react with H2O2
Cr3+ colour
green
how is Cu2+ reduced to Cu+
react with I-
what is formed in this reaction?
CuI precipitate
brown solution
colour of Cu2+
pale blue
colour of CuI
white precipitate
colour of I2
brown solution
reaction of Cu2+ and I-
what is Cu+ able to do?
as it is very unstable it is able to disproportionate into Cu and Cu2+ ions
so it is both oxidised and reduced
reaction when Cu2O reacts with H2SO4