18.5 Rate constants and temp Flashcards
what effect does increasing the temperature have on the rate?
increasing temp shift Boltzmann curve to the right meaning more molecules have an energy higher than the activation energy
increasing temp increases kinetic energy in particles which means they move quicker and collide more frequently
what is the gas constant?
8.31
what is the Arrhenius equation?
what does the exponential factor represent?
the proportion of molecules with an energy exceeding the activation energy
what is the logarithmic form of the Arrhenius equation?
how can the Arrhenius equation be linked to a straight line?
what is the y-axis in an Arrhenius plot?
ln K
what is the x-axis in an Arrhenius plot?
1/T
what is the gradient in an Arrhenius plot?
what is the y-intercept in an Arrhenius plot?
ln A
Arrhenius plot
how do you calculate activation energy from ln K graph?
8.31 x -(gradient)
how do you calculate the pre-exponential factor from a ln K graph?
e to the power of the y-intercept