24.5 redox and qualitative analysis Flashcards

1
Q

what happens in the reaction between Fe2+ and MnO4-

A

Fe2+ is oxidised to Fe3+
MnO4- is reduced to Mn2+

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2
Q

what is the colour change when MnO4- is reduced?

A

purple to colourless

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3
Q

what happens when Fe3+ ions react with iodide ions?

A

Fe3+ is reduced to Fe2+
I- is oxidised to I2

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4
Q

what is the colour change when Fe3+ is reduced to Fe2+?

A

orange-brown to pale-green

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5
Q

what is the colour change when I- is oxidised to I2?

A

colourless to brown

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6
Q

what is the relationship between E value and reduction?

A

the more positive an E value is, the more likely reduction will occur in that reaction

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7
Q

what happens when Cr2O7 2- reacts with Zn?

A

Cr2O7 2- is reduced to Cr3+
Zn is oxidised to Zn2+

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8
Q

what is the colour change when Cr2O7 2- is reduced to Cr3+?

A

orange to green

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9
Q

what happens when Cr3+ reacts with excess Zn?

A

Cr3+ is reduced to Cr2+

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10
Q

what is the colour change when Cr3+ is reduced to Cr2+?

A

green to pale blue

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11
Q

what happens when H2O2 reacts with Cr3+ ?

A

Cr3+ is oxidised to CrO4 2-
oxygen is reduced

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12
Q

what happens when Cu2+ reacts with I- ?

A

I- is oxidised to I2
Cu2+ is reduced to Cu+

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13
Q

what colour change occurs when Cu2+ is reduced to Cu+ ?

A

pale blue to white precipitate

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14
Q

how are transition metal ions identified?

A

by adding NaOH and observing the colour changes

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15
Q

how are ammonium ions identified?

A

NaOH is added and solution is heated
turns red litmus paper blue

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16
Q

how to oxidise Fe2+ to Fe3+?

A

add MnO4- ions

17
Q

how to reduce Fe3+ to Fe2+?

A

add I- ions

18
Q

how to reduce CrO4 2- to Cr3+?

A

add Zn

19
Q

how to oxidise Cr3+ to CrO4 2-?

A

add H2O2

20
Q

how to reduce Cu2+ to Cu+?

A

add I-