24.3 stereoisomerism in complex ions Flashcards
what isomerism do complex ions show?
cis-trans
optical
which shaped complex ions does cis-trans occur in?
octahedral
square planar
what is cis isomerism in a square planar ion?
the two identical ligands are found adjacent to each other
what is trans isomerism in an square planar ion?
the two identical ligands are found opposite to each other
what is cis isomerism in a monodentate octahedral ion?
the two identical ligands are found adjacent to each other
what is trans isomerism in a monodentate octahedral ion?
the two identical ligands are found opposite to each other
what is cis isomerism in a bidentate octahedral ion?
the two identical ligands are found adjacent to each other
what is trans isomerism in a bidentate octahedral ion?
the two identical ligands are found opposite to each other
what are the conditions for optical isomerism?
- octahedral complex
- contains 2 or more bidentate ligands