24.3 stereoisomerism in complex ions Flashcards

1
Q

what isomerism do complex ions show?

A

cis-trans
optical

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2
Q

which shaped complex ions does cis-trans occur in?

A

octahedral
square planar

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3
Q

what is cis isomerism in a square planar ion?

A

the two identical ligands are found adjacent to each other

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4
Q

what is trans isomerism in an square planar ion?

A

the two identical ligands are found opposite to each other

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5
Q

what is cis isomerism in a monodentate octahedral ion?

A

the two identical ligands are found adjacent to each other

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6
Q

what is trans isomerism in a monodentate octahedral ion?

A

the two identical ligands are found opposite to each other

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7
Q

what is cis isomerism in a bidentate octahedral ion?

A

the two identical ligands are found adjacent to each other

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8
Q

what is trans isomerism in a bidentate octahedral ion?

A

the two identical ligands are found opposite to each other

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9
Q

what are the conditions for optical isomerism?

A
  • octahedral complex
  • contains 2 or more bidentate ligands
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