19.3 Controlling the position of the equilibrium Flashcards
increasing temperature in an endothermic reaction
increases Kc
increasing temperature in an exothermic reaction
decreases Kc
why does increasing the temperature in an endothermic reaction increase the Kc?
increasing temperature in an endothermic reaction causes the EQ to shift to the right
the concentration of the products gets larger
and
the concentration of the reactants gets smaller
means a larger value for Kc
why does increasing the temperature in an exothermic reaction decrease the Kc?
increasing temp in an exothermic reaction causes the EQ to shift to the left
the concentration of the products gets smaller
and
the concentration of the reactants gets bigger
means a smaller value for Kc
is Kc affected by pressure and concentration?
no
it remains constant
what does changing the pressure or concentration affect?
the ratio of products to reactants
the EQ then changes to return the ratio back to the Kc value
what happens when the concentration of the reactants increases?
you get a smaller value for the ratio of products to reactants
this ratio is smaller than the Kc value so no longer in equilibrium
how does the EQ return the ratio to Kc value?
concentration of products increases
concentration of reactants decreases
thus shifting the EQ to the right
causes the ratio to increase back to the Kc value
back to equilibirum
do catalysts affect the Kc?
no
features of catalyst
increase the rate of a reaction
BUT not the EQ
catalysts speed up both the forward and reverse reactions in an EQ by the same factor