24.1 d-block elements Flashcards

1
Q

which orbital do d-block elements have their highest electron in?

A

d orbitals

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2
Q

what are the properties of d-block elements?

A

they are metallic
high melting point
shiny
conduct electricity

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3
Q

which d-block elements have a different electron configuration?

A

chromium
copper

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4
Q

why do chromium and copper have a different electron configuration?

A

an electron from it’s 4s orbital is given to the 3d orbital for stability

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5
Q

what is the order of losing electrons in d-block elements?

A

the 4s is emptied first
then the 3d

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6
Q

what is the order of gaining electrons in d-block elements?

A

the 4s is filled first
then the 3d

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7
Q

what is a transition element?

A

d-block elements that forms at least one ion with a PARTIALLY filled d-orbital

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8
Q

which elements are d-block elements but not transition metals?

A

Scandium
Zinc

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9
Q

what ion does Sc form?

A

3+

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10
Q

what is the electron configuration of Sc3+?

A

1s2 2s2 2p6 3s2 3p6

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11
Q

why is Scandium not a transition metal?

A

because it’s d-orbitals are empty as they have no electrons

therefore it’s d orbitals are not partially occupied so it cannot be a transition metal

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12
Q

what ion does Zn form?

A

2+

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13
Q

what is the electron configuration of Zn2+?

A

1s2 2s2 sp6 3s2 3p6 3d10

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14
Q

why is Zinc not a transition metal?

A

it has fully occupied d orbitals

therefore it’s d orbitals are not partially occupied so it cannot be a transition metal

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15
Q

what are the properties of transition metals?

A
  • form compounds with different oxidation states
  • form coloured compounds
  • can act as catalysts
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16
Q

what is the relationship between colour and oxidation number?

A

different oxidation numbers for the same transition metal can give different colours

17
Q

Fe(II) colour

A

pale green

18
Q

Fe(III) colour

A

yellow

19
Q

Cr(III)

A

green

20
Q

Cr(VI)

A

yellow/orange

21
Q

which processes use a transition metal as a catalyst?

A

haber process
contact process
hydrogenation
decomposition of H2O2

22
Q

catalyst for Haber process?

A

iron

23
Q

catalyst for contact process?

A

vanadium (V) oxide

24
Q

catalyst for hydrogenation?

A

nickel

25
Q

catalyst for decomposition of H2O2?

A

MnO2