2 BM - Carbohydrates Flashcards
What are the isomers of Glucose?
Alpha-glucose
Beta-glucose
What is a reducing sugar?
A sugar which is able to donate electrons to another chemical.
What types of sugars are reducing?
All monosaccharides
Some disaccharides
What is a non-reducing sugar?
A sugar which is not able to donate electrons to another chemical.
What types of sugars are non-reducing?
All polysaccharides
Some disaccharides
What is the test for identifying a reducing sugar?
1 - add 2cm³ of food sample to be tested into test tube. If the sample is not liquidised, grind it up in water before adding to test tube.
2 - Add an equal volume of benedict’s reagent
3 - Heat the mixture in a gently boiling water bath for 5 minutes.
What is the test for identifying a non-reducing sugar?
1 - add 2cm³ of food sample to be tested into test tube. If the sample is not liquidised, grind it up in water before adding to test tube.
2 - Add an equal volume of benedict’s reagent
3 - Heat the mixture in a gently boiling water bath for 5 minutes.
4 - If there is no colour change, add acid and then alkali to the sample and repeat steps 1 - 3.
What type of molecules are polysaccharides?
Macromolecules.
- Slightly/ insoluble in water
- formed by condensation reactions
- non-reducing sugars
What are the polysaccharides of α-glucose?
Glycogen
Starch (amylose and amylopectin)
What are the polysaccharides of β-glucose?
Cellulose
Glycogen ((7))
- Insoluble
- Energy store in animals + fungi
- 1 - 4 & 1 - 6 linked glucose
- Coiled structure (good for storage)
- Polymer of α-glucose
- larger surface area for enzymes to hydrolyse glycosidic bonds & this allows glucose to be released quickly.
- similar to amylopectin but it has more branches
Starch ((4))
- Polymer of α-glucose
- Made from amylose & amylopectin
- Insoluble
- Energy store in plants
Amylopectin ((4))
- Polymer of α-glucose
- A component of starch alongside amylose
- Long branched chains (large surface area)
- Side chains
Amylose ((5))
- Polymer of α-glucose
- 1 - 4 linked glucose molecules
- Coils into a helix for storage (compact for storage)
- Stabilised by H bonds
- Iodine can get ‘trapped’ in
Cellulose
- Polymer of β-glucose
- Insoluble
- Long unbranched chains (straight chains)
- Cellulose + Cellulose form H bonds to create microfibrils (strong but flexible - valuable to structure)