15.1.2 - Ligands and complexes Flashcards

1
Q

What is different about the electronic configuration of chromium and copper?

A

they only have one electron in their 4s orbital instead of 2.

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2
Q

What type of bonds do ligands form with central metal ion?

A

Dative covalent.

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3
Q

What are some common types of ligands?

A

water
hydroxide
ammonia
chloride

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4
Q

What are the names of water and ammonia in complexes?

A

Water = aqua
Ammonia = ammine

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5
Q

What is the coordinate number of a linear complex and what metal usually forms these?

A

2

Ag+

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6
Q

What ions usually form a square planar complex?

A

Platinum (II)
Nickel (II)

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7
Q

What is the coordinate number of a tetrahedral complex and what ligand usually forms these?

A

4

Cl-

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8
Q

What is the coordinate number of an octahedral compound and what ligands usually forms these?

A

6

water and ammonia

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9
Q

What is the name given to copper and iron compounds when the overall charge is negative?

A

copper = cuprate
Iron = ferrate

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10
Q

What is the bond angle in the following shapes of transition metal complexes?
Linear
square planar
tetrahedral
Octahedral

A

linear = 180
Square planar = 90
Tetrahedral = 109.5
Octahedral = 90

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