15.1.2 - Ligands and complexes Flashcards
What is different about the electronic configuration of chromium and copper?
they only have one electron in their 4s orbital instead of 2.
What type of bonds do ligands form with central metal ion?
Dative covalent.
What are some common types of ligands?
water
hydroxide
ammonia
chloride
What are the names of water and ammonia in complexes?
Water = aqua
Ammonia = ammine
What is the coordinate number of a linear complex and what metal usually forms these?
2
Ag+
What ions usually form a square planar complex?
Platinum (II)
Nickel (II)
What is the coordinate number of a tetrahedral complex and what ligand usually forms these?
4
Cl-
What is the coordinate number of an octahedral compound and what ligands usually forms these?
6
water and ammonia
What is the name given to copper and iron compounds when the overall charge is negative?
copper = cuprate
Iron = ferrate
What is the bond angle in the following shapes of transition metal complexes?
Linear
square planar
tetrahedral
Octahedral
linear = 180
Square planar = 90
Tetrahedral = 109.5
Octahedral = 90