1 Intro To Hazmat Flashcards
OSHA reg in title 29 code of federal regulations (CFR) 1910.120
Hazardous waste operations and emergency response (HAZWOPER)
Paragraph q for awareness and operations level
Hazardous material
Any material or substance that poses an unreasonable risk to the health and safety of persons and the environment if not properly controlled during handling, storage, manufacture, processing, packaging, transportation, use or disposal.
Dangerous goods
What hazmat is referred to in Canada and other countries
OSHA
Occupational safety and health administration
Federal agency that develops and enforces workplace safety standards
OSHA and epa require special training for first responders to hazmat,
HAZWOPER
Epa regulation in title 40 CFR 311, worker protection provides
Protection for responders in states not covered by osha
Standards of nfpa are not law and are only used if
Adopted by authority having jurisdiction AHJ
A first responder by law, the employer must meet hazwoper requirements true false
True
Nfpa 472 and HAZWOPER identifies two levels of training
Awareness and operations
Operations level
Training established by Oshawa allowing first responders to take defensive action at hazmat incidents
Nfpa 472 May be trained to core competency levels, operations core or beyond, operations mission specific. Some of the specifics competencies are
Ppe Mass Decon Technical Decon Evidence preservation and sampling Product control Air monitoring and sampling Victim rescue and recovery Response to illicit lab incidents
OSHA defines three levels above operations level
Hazmat tech
Hazmat specialist
On scene IC OIC
Nfpa 472 id’s five levels above operations level
Hazmat tech plus three specialties Hazmat branch officer Hazmat branch safety officer Hazmat IC Private sector specialist employee
OSHA considered personnel trained to awareness and operations level to be
First responders
Nfpa 472 uses what word to refer to someone at the awareness level
Personnel as opposed to the Oshawa first responder title
Individuals trained to awareness level are first arriving to scene and are expected to assume what responsibilities at hazmat incident
Recognize presence of possible hazmat
Recognize type of container at site and material in it
Transmit info to appropriate or call for appropriate authority
Id actions to protect themselves and others
Establish scene control by isolating area and denying entry
Operations level includes awareness responsibilities plus
Id hazmat involved
Analyze incident to determine nature and extent of problem
Protect themselves, public, environment and property from release
Plan a response or defensive action to address problems
Implement planned response to mitigate or control release at safe dist
Evaluate progress of actions to ensure objectives are met
Operations can perform offensive actions with
Gasoline
diesel,
Natural gas
Lpg
Acute exposure
Single or several repeated exposures within short time period
Chronic exposure
Long term or reoccurring
Acute health effects
Show up in hours or days
Chronic health effects
Long term that take years to develop. Like cancer
The following have potential to cause harm TRACEM
Thermal hazards Radiological Asphyxiation Chemical Etiological/biological Mechanical
Chemical hazards
Poison/toxin Corrosives Irritants Convulsants Carcinogens Sensitizers/allergens
Oxidization
Chen process that occurs when substance combines with oxygen
Rust
Polymerization
Rxn where two or more molecules chemically combine forming larger molecules often violent rxn
Liquefied gas
When at charging pressure is partially liquified at 70 degrees f
Cryogen, sometimes called refrigerated liquefied gas
Turns into liquid at or below -130 f at 14.7 psi
Common cryogenics
Liquid oxygen, LOX nitrogen Helium Hydrogen Argon Liquified natural gas LNG
Fluorine is also a cryogenic, but has hazardous properties including
Corrosive, oxidizer and poison
Corrosive material,
Burn irritate or destroy skin and corrode steel
Cryo spills will
Boil and/or pool and turn into gas do vapor cloud
Anhydrous ammonia
Refrigerant in storage facilities, cold injuries, toxic, vapors can ignite
Molten aluminum. Is shipped in containers at over what temp
1300f
Dot defines elevated temp material as when offered for transportation or when done so in bulk it has one of following properties
Liquid phase at above 212f
Liquid phase with flashpoint at or above 100f and intentionally heated for transportation. Or is transported above flashpoint
Solid phase at or above 464f