Unit 1 - Lecture 3 Topic 2 Flashcards
Textile fibres are composed of small units called ________ linked to form long chains called ________.
Monomers, polymers
What are fibre properties influenced by?
The nature of the monomers, length of chain (known as the degree of polymerization), and arrangement of chains in the fibre.
Degree of Polymerization:
The length of a polymer, or how many times the monomer repeats along a chain. It can range from 500 to over 10 000. Degree of polymerization can influence fibre strength.
Fibre Crystallinity:
Polymer chains in the fibre can be configured in crystalline regions or amorphous regions. A typical fibre has both crystalline & amorphous regions.
Crystalline Regions:
Small or regular units that allow close, ordered packing of polymer chains that zip together. These chains are held together by polar hydrogen bonds and non-polar Van der Waals bonds.
Amorphous Regions:
Large units with bulky side-groups that pack in disordered arrangements in polymer chains. These regions have voids between molecular chains with low inter-chain bonding which allows space for dyes and other treatments.
Fibre Orientation:
Molecular chains which are parallel to each other and to the fibre’s lengthwise axis are oriented. A “highly oriented” fibre is when a high proportion of polymers are aligned with the fibre axis.
Stretching/Drawing of Fibres:
Used to increase orientation in manufactured fibres, immediately after extrusion. This reduces fibre diameter and increases durability.