U1-2-2 - Electronic Configuration Flashcards

1
Q

Aufbau principle

A

Electrons fill orbitals in order of increasing energy.

E.g. 1s before 2s, 2s before 2p.

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2
Q

4s orbitals are an exception when filling orbitals because ___________.

A

they are filled before 3d.

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3
Q

Hund’s rule

A

Electrons first fill degenerate orbitals singly with parallel spins.

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4
Q

Pauli exclusion principle

A

No two ein one atom can have the same set of four quantum numbers.

(So no orbital can hold more than two e<strong>−</strong> and these two e must have opposite spins.)

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5
Q

Aluminium has the electronic configuration [Ne] 3s2 3p1.

What does [Ne] mean?

A

Shorthand for electronic configuration of neon: 2, 8.

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6
Q

Ground state

A

Lowest energy electronic configuration (default)

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7
Q

Name the principle described

Electrons fill orbitals in order of increasing energy.

E.g. 1s before 2s, 2s before 2p.

A

Aufbau principle

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8
Q

Name the principle described

Electrons first fill degenerate orbitals singly with parallel spins.

A

Hund’s rule

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9
Q

Lowest energy electronic configuration (default)

A

Ground state

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10
Q

Name the principle described

No two ein one atom can have the same set of four quantum numbers.

(So no orbital can hold more than two e<strong>−</strong> and these two e must have opposite spins.)

A

Pauli exclusion principle

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11
Q

What decides which block (s, p, d, f) in the periodic table an element is placed in?

A

Last occupied subshell

(e.g. 1s2 2s2 2p6 = p block)

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12
Q

The s block contains __________.

A

groups 1 and 2, and helium

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13
Q

The p block contains ___________.

A

groups 3 – 8, except helium

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14
Q

The d block contains __________.

A

the transition metals

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15
Q

The f block contains __________.

A

lanthanides and actinides

Subset of transition metals shown under the periodic table

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16
Q

The more stable the electronic configuration, the _____________ the ionisation energy.

A

higher

17
Q

State three features that make an electronic configuration stable.

A

Ends in a full shell (e.g. 2nd shell)

or full subshell (e.g. 3p6)

or half-filled subshell (e.g. 2p3).

18
Q

The more stable the electronic configuration, the ____ reactive the species.

A

less