U1-2-1 - Quantum Numbers and Atomic Orbitals Flashcards
Principal quantum number, n
Energy level the electron resides in

Angular momentum quantum number, l
Defines the shape of a subshell (e.g. spherical)
Quantum number l can take values __________.
from 0 to n – 1
When l = 0, the subshell is marked with the letter __.
s
When l = 1, the subshell is marked with the letter __.
p
When l = 2, the subshell is marked with the letter __.
d
When l = 3, the subshell is marked with the letter __.
f
Subshells are further split into energy levels known as orbitals.
What is an orbital?
An orbital describes where an e− is likely to be found around a nucleus.
Each orbital can hold a maximum of _____ e−.
two
Shape of s orbital
Spherical

Shape of p orbital
Dumbbell/8

Shape of d orbital
Two intersecting p orbitals

Arrange the subshells in order of increasing energy:
d, s, f, p
s, p, d, f
In an isolated atom, all orbitals in a subshell are degenerate. This means they are ___________.
of equal energy
Magnetic quantum number, mℓ
Defines orbital orientation in space (e.g. along y axis, or xy plane)
mℓ can have values __________.
from −ℓ to +ℓ
(e.g. if ℓ = 1, mℓ = −1, 0, +1)
Number of s orbitals in an s subshell
1
(1 orientation possible for a sphere)
Number of p orbitals in a p subshell
3
(along x, y and z axes)

Number of d orbitals in a d subshell
5

Spin magnetic quantum number, ms
Describes electron spin (+1/2 or –1/2)