Topic 4: Cellulose and plant cell wall Flashcards
What are the 2 isomers of glucose? (2 points)
- Alpha glucose / α glucose
2. Beta glucose / ß glucose
The _ glucose molecule has two hydroxyl groups ________ to one another.
α (alpha)
adjacent
Cellulose if made from _____ _-________ __________.
1,4 glycosidic bonds cannot be made because the two ________ groups are not next to each other.
One glucose molecule must be ________ (flipped) so bonding can take place.
Then a __________ ________ joins two β-glucose monomers together.
A _ , ________ bond forms
Cellulose if therefore an ___________ molecule.
many β-glucose molecules
(beta glucose)
hydroxyl
inverted
condensation reaction
β 1,4 glycosidic
unbranched
Describe the structure of starch (4 points)
- Many alpha glucoses
- Branched
- 1,4 and 1,6 glycosidic bonds
- Compact
What is the function of starch? (1 point)
- Energy storage molecule in plants as it is easily hydrolysed to release glucose.
What are the properties of starch? (1 point)
- Insoluble in water (no osmotic effect)
Describe the structure of cellulose (4 points)
- Made of many beta glucoses
- Every alternate beta glucose is inverted
- Unbranched
- 1,4 glycosidic bonds - form between 2 OH groups with removal of water
What is the function of cellulose? (2 points)
- Cellulose microfibrils are a component of the plant cell wall for strength and support to plant cells and allow turgor (for further support)
What are the properties of cellulose? (2 points)
- Insoluble in water
2. High tensile strength
Key Summary: What are the similarities between the structure of starch and cellulose?
(3 similarities)
- Both made of glucose molecules
- Both have 1,4 glycosidic bonds
- Both are polysaccharides
Key Summary: What are the differences between the structure of starch and cellulose?
(4 differences)
- starch is made of alpha glucose, cellulose of beta glucose
- starch is branched (amylopectin) with 1,6 glycosidic bonds, cellulose is unbranched/straight chain
- starch has alpha 1,4 glycosidic bonds, cellulose has beta 1,4 glycosidic bonds
- in starch all molecules are in the same orientation, but in cellulose every alternate glucose is inverted
Key Summary: Describe the structure/formation of a cellulose molecule. (4 points)
- many beta glucoses
- joined by beta 1,4 glycosidic bonds between 2 OH groups in condensation reactions with removal of water
- every alternate glucose molecule is inverted
- long unbranched/straight polysaccharide chain
How does cellulose form the cell wall? (5 steps - start from cellulose being formed)
- Beta glucose forms cellulose molecules
- Cellulose molecules form microfibrils
- Microfibrils are arranged at angles in layers
- Microfibrils are bonded together in a matrix of hemicelluloses and pectins
- Lignin (secondary thickening) added to form the secondary cell wall
What is a cellulose molecule? (3 points)
- Long chains of several thousand beta glucose molecules,
- every alternate one inverted,
- joined by 1,4 glycosidic bonds in condensation reactions.
Many (60-70) cellulose _________ (long chains of glucose) lie parallel to each other and are cross linked by _________ _______ to form a cellulose _________.
molecules
hydrogen bonds
microfibril
_________ ______ form between δ+ _______ atoms and δ– ______ atoms on ____ groups that stick out from the beta glucoses on adjacent cellulose molecules.
This is called ______-________
Hydrogen bonds
hydrogen
oxygen
OH
cross-linking
Key Summary: Describe the {structure/formation} of a cellulose microfibril (5 steps)
- beta glucoses joined by β 1,4 glycosidic bonds in condensation reactions,
- with every alternate glucose molecule inverted,
- forming an {unbranched chain/cellulose molecule}.
- 60-70 cellulose molecules lie parallel to each other
- and are cross-linked and held together by hydrogen bonds between polar groups on beta glucoses of adjacent cellulose molecules.