Structural Isomerism Flashcards
There are three different types of structural isomerism:
Chain isomerism
Positional isomerism
Functional group isomerism
Structural isomers are compounds that
have the same molecular formula but different structural formulae
E.g. propene and cyclopropane
Chain isomerism is when compounds have
the same molecular formula, but their longest hydrocarbon chain is not the same
This is caused by branching
E.g. pentane and 2,2-dimethylpropane
Positional isomers arise from differences in the position of a
functional group in each isomer
The functional group can be located on different carbons
For example, butan-1-ol and butan-2-ol
When different functional groups result in the same molecular formula, ……………. arise
functional group isomers
The isomers have very different chemical properties as they have
different functional groups
For example, butanol and ethoxyethane