Interpreting an IR(infrared spectrum) Spectrum Flashcards

1
Q

Infrared (IR) spectroscopy is a technique used to

A

identify compounds based on changes in vibrations of atoms when they absorb IR of certain frequencies

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2
Q

A spectrophotometer irradiates the

A

sample with electromagnetic waves in the infrared region and then detects the intensity of the wavelength of IR radiation which goes through the sample

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3
Q

All organic molecules absorb IR radiation and depending on which energies of radiation are absorbed, bonds between atoms will vibrate by

A

stretching, bending and twisting

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4
Q

The molecules will only vibrate at a specific frequency
The resonance frequency is the

A

specific frequency at which the molecules will vibrate to stimulate larger vibrations

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5
Q

Depending on the rest of the molecule, each vibration will absorb specific wavelengths of IR radiation which are also shown as the

A

reciprocal of the wavelength

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6
Q

IR radiation wavelengths measurements

A

wavenumber (cm-1)

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7
Q

Particular absorbance have characteristic

A

widths (broad or sharp) and intensities (strong or weak)
For example, hydrogen bonds cause the O-H bonds in alcohols and carboxylic acids to be broad whereas the C-O bond in carbonyl (C=O) groups have a strong, sharp absorbance peak

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8
Q

Due to some absorption bands overlapping each other, other analytical techniques such as

A

mass spectroscopy should be used alongside IR spectroscopy to identify an unknown compound

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