Interpreting an IR(infrared spectrum) Spectrum Flashcards
Infrared (IR) spectroscopy is a technique used to
identify compounds based on changes in vibrations of atoms when they absorb IR of certain frequencies
A spectrophotometer irradiates the
sample with electromagnetic waves in the infrared region and then detects the intensity of the wavelength of IR radiation which goes through the sample
All organic molecules absorb IR radiation and depending on which energies of radiation are absorbed, bonds between atoms will vibrate by
stretching, bending and twisting
The molecules will only vibrate at a specific frequency
The resonance frequency is the
specific frequency at which the molecules will vibrate to stimulate larger vibrations
Depending on the rest of the molecule, each vibration will absorb specific wavelengths of IR radiation which are also shown as the
reciprocal of the wavelength
IR radiation wavelengths measurements
wavenumber (cm-1)
Particular absorbance have characteristic
widths (broad or sharp) and intensities (strong or weak)
For example, hydrogen bonds cause the O-H bonds in alcohols and carboxylic acids to be broad whereas the C-O bond in carbonyl (C=O) groups have a strong, sharp absorbance peak
Due to some absorption bands overlapping each other, other analytical techniques such as
mass spectroscopy should be used alongside IR spectroscopy to identify an unknown compound