Electrophilic addition Flashcards
Electrophilic addition is the addition of an
electrophile to a double bond
What happens to the bond after the electrophile attacks
The C=C double bond is broken, and a new single bond is formed from each of the two carbon atoms
Electrophilic addition reactions include the addition of:
Steam (H2O (g))
Hydrogen halide (HX)
Halogen
The double bond in alkenes is an area of high electron density (there are four electrons found in this double bond)
This makes the double bond susceptible to attack by
electrophiles (electron-loving species)
An electrophilic addition is the addition of an electrophile to a double bond
Electrophilic addition of hydrogen bromide
A molecule of hydrogen bromide (HBr) is polar as the hydrogen and bromine atoms have different electronegativities
The bromine atom has a stronger pull on the electrons in the H-Br bond
As a result of this, the Br atom has a partial ……………and the H atom a partial ……….charge
negative
positive
In an addition reaction, the H atom acts as an electrophile and accepts
a pair of electrons from the C=C bond in the alkene
After hydrogen attacks the double bond what happens to bromine
The H-Br bond breaks heterolytically, forming a Br- ion
After the hydrogen has attacked double bond and bromine ion has been made
leads to the formation of a
carbocation intermediate which reacts with the Br- (nucleophile)