Redox reactions Flashcards
What are the principles of metabolic pathways?
- Complex transformations occur in a separate series of reactions
- Each reaction is catalyzed by a specific enzyme
- Many metabolic pathways are similar in all organisms
- In eukaryotes, metabolic pathways are compartmentalized in specific organelles
- Key enzymes can be inhibited or activated to alter the rate of the pathway
What are the changes in energy during redox reactions?
- Oxidation-Reduction - one substance transfers electrons to another substance. oxidation and reduction always work together
- reduction is gaining of electrons while oxidation is the loss of them
Electron acceptors in biological redox reactions
Hydrogens are thought of as electrons
Carbon containing molecules
Gains H, loses O, it’s been reduced and is an oxidizing agent
Loses H, gains O, it’s been oxidized and is a reducing agent
Oxidizing agent and reducing agent
Oxidizing: NADH + H+ + 1/2 O2 = NADH + H2O
Reducing: NAD+ H+ 2e- = NADH
Glycolysis
Takes place in the cytoplasm, converts 2 pyruvates and produces 2 ATP and 2 NADH, a 10 step process
10 step glycolysis process
1-5 requires 2 ATP, steps 6-10 harvest ATP, and yields 4 ATP and 2 NADH
In the glycolysis process
2 metabolic ways happen: Oxidation-reduction and substrate level phosphorylation. Oxidation-reduction releases energy by trapping glucose oxidation, which restricts ATP and produces NADH. Substrate level phosphorylation releases energy which transfers a phosphate from the substrate to ADP, which then forms ATP