Rate Equations Flashcards
rate equation
Rate = k [A]m [B]n
total order
m + n
zero order
conc has no effect on rate
first order
rate is directly proportional to conc
second order
rate is directly proportional to square of conc
rate constant increases when
temp increases
bigger k = faster reaction
Arrhenius equation
k = Ae ^ -Ea/RT
k = rate constant A = Arrhenius constant e = mathematical constant Ea = activation energy R = gas constant T = temp/K
what are the rate constant and rate of reaction directional proportional to?
molecules with E > Ea
higher temp = ?
higher rate constant
higher rate of reaction
Arrhenius rearranged
lnk = lnA - Ea/RT
increased Ea = ?
decreased k
gradient
- Ea/R
y intercept
lnA
y = mx + c
lnk = (-Ea/R) (1/T) / lnA
why do we use initial rate
exact conc of reactants is known
determining rate equation experimentally
temp must remain constant
only reactant conc altered
draw cone-time graph
draw tangent at 0