Kinetics Flashcards

1
Q

activation energy

A

min energy particles need to collide and start a reaction

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2
Q

in order for a reaction to occur, particles must..

A

collide in right orientation w sufficient energy (>Ea)

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3
Q

bond making

A

exothermic; releases energy

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4
Q

bond breaking

A

endothermic; aborbs energy

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5
Q

maxwell

A

at origin; most probable-average-Ea; area=no. of particles; don’t touch x-axis (no max energy)

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6
Q

maxwell - temp

A

lower + wider graph; higher average energy. small temp=big change. more collisions + higher energy collisions

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7
Q

maxwell- con + pres

A

closer; more freq collisions; same shape just higher; same proportion >Ea

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8
Q

maxwell - catalyst

A

changes Ea. same amount of product faster + at lower temp. more particles have >Ea

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9
Q

small temp inc = large effect

A

many more molecules collisions

with E ≥ E act

more molecules have energy greater than activation energy

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10
Q

rate of reaction

A

change in con in given time

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11
Q

why would a reaction still continue at a constant temp

A

Molecules gain energy (or always some molecules have E > Ea)

Due to collisions

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12
Q

why do collisions decrease energy of a molecule

A

Cause some molecules to slow down or lose energy

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13
Q

measure rate of reaction where a gas is produced

A

measure volume of gas / mass lost

at regular time intervals

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14
Q

define ‘catalyst’

A

speeds up rate of reaction

without being used up/ chemically unchanged at the end

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15
Q

how does a catalyst work

A

provides alt reaction pathway

with lower activation energy

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