Kinetics Flashcards
activation energy
min energy particles need to collide and start a reaction
in order for a reaction to occur, particles must..
collide in right orientation w sufficient energy (>Ea)
bond making
exothermic; releases energy
bond breaking
endothermic; aborbs energy
maxwell
at origin; most probable-average-Ea; area=no. of particles; don’t touch x-axis (no max energy)
maxwell - temp
lower + wider graph; higher average energy. small temp=big change. more collisions + higher energy collisions
maxwell- con + pres
closer; more freq collisions; same shape just higher; same proportion >Ea
maxwell - catalyst
changes Ea. same amount of product faster + at lower temp. more particles have >Ea
small temp inc = large effect
many more molecules collisions
with E ≥ E act
more molecules have energy greater than activation energy
rate of reaction
change in con in given time
why would a reaction still continue at a constant temp
Molecules gain energy (or always some molecules have E > Ea)
Due to collisions
why do collisions decrease energy of a molecule
Cause some molecules to slow down or lose energy
measure rate of reaction where a gas is produced
measure volume of gas / mass lost
at regular time intervals
define ‘catalyst’
speeds up rate of reaction
without being used up/ chemically unchanged at the end
how does a catalyst work
provides alt reaction pathway
with lower activation energy