Practicals Flashcards

1
Q

Define a primary/secondary/tertiary alcohol

A

C-OH where C atom is bonded to 1/2/3 akyl groups

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2
Q

Outline the oxidation of primary alcohols through distillation

A

R-OH +[O] -(distill)-> R-CHO + [O] -(reflux)-> R-COOH

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3
Q

Outline the oxidation of primary alcohols through reflux

A

R-OH + 2[O] -(reflux)-> R-COOH

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4
Q

Outline the oxidising agent used for the distillation of primary alcohols

A

Tollens = silver mirror
or
Fehling’s = brick red

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5
Q

Outline a reducing agent for alcohols and/or aldehydes

A

Kr2Cr2O7
H2SO4

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6
Q

Outline the colour change when a primary alcohol is oxidised with K2Cr2O7

A

Orange -> green

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7
Q

List what’s used for the distillation apparatus

A
  1. Pear shaped flask
  2. Anti-bumping granules
  3. Bung
  4. Thermometer
  5. Condenser
  6. e- heater
  7. Ice bath
  8. Flask
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8
Q

Why are anti-bumping granules used for distillation/reflux?

A

Only make small bubbles form = smooth boiling

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9
Q

Why is an e- heater used for distillation?

A

Alcohol used is flammable (risk)

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10
Q

Why does H2O in the condenser enter from the bottom and leave the top?

A

Ensure condenser completely fills

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11
Q

Why is an ice bath used at the end of distillation?

A

Ensure that volatile reactants/products don’t escape as a gas

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12
Q

Define reflux

A

Continual evaporation + condensation

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13
Q

List what’s used in the reflux apparatus

A
  1. Pear shaped flask
  2. Anti-bumping granules
  3. Bung
  4. Condenser
  5. e- heater
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14
Q

What organic liquid is normally purified?

A

Cyclohexanol -> cyclohexene

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15
Q

Which has a higher bp and why? Cyclohexanol or cyclohexene?

A

Cyclohexanol
Cyclohexanol = H bonds from R-OH
Cyclohexene = VDWs
H bonds > VDWs

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16
Q

Outline the steps that occur for the elimination of cyclohexanol (not like usual mechanism)

A
  1. H+ from catalyst (H3PO4) attacked by e- pair on R-OH
  2. H of adjacent C to C-OH2 donates e- pair to form C=C
  3. e- pair donates to O+ to form cyclohexene, H2O & reformed H+
17
Q

What apparatus is used for the 1st stage of purification of an organic liquid?

A

Distillation

18
Q

Outline the 2nd step of the purification of an organic liquid

A

Add a base (Na2CO3) -> open tap to release CO2

19
Q

Outline the 3rd step of the purification of an organic liquid and it’s purpose

A

Put mixture in separating funnel
Cyclohexanol = top layer
H3PO4(aq) = bottom layer (more dense)
Cyclohexanol separates
Use tap to drain (aq) layer

20
Q

Outline the 4th step of the purification of an organic liquid

A

+ drying agent (CaSO4) to absorb H2O & other aqueous substances

21
Q

Outline the 5th step of the purification of an organic liquid

A

Distill again

22
Q

Outline the organic solid that’s normally purified

23
Q

Outline the reagents and mechanism that occurs for the formation of Aspirin

A

2-hydroxybenzoic acid + ethanoic anhydride
Nucleophilic addition elimination

24
Q

Outline the steps for the nucleophilic addition elimination to form aspirin

A
  1. :OH on 2-hydroxybenzoic acid attacks C+ on ethanoic anhydride - C=O breaks
  2. O-H on acid breaks to remove O+. :O- on anhydride forms C=O again, breaking C-O bond
    Aspirin forms
  3. H+ from O-H forms with broken of CH3COO- from anhydride to form CH3COOH
25
Q

What practical is used for the purification of an organic solid?

A

Recrystallisation

26
Q

Outline the 1st step of the purification of an organic solid

A

Dissolve aspirin in min amount of hot solvent (ethanol)

27
Q

Outline the 2nd stage of the purification of an organic solid

A

Gravity filtration - remove insoluble impurities
Use funnel and filter paper

28
Q

Outline the 3rd stage of the purification of an organic solid

A

Put solvent, aspirin & soluble impurities in ice bath
Aspirin crystallises out

29
Q

Outline the 4th stage of the purification of an organic solid

A

Wash aspirin in ice cold solvent under reduced Pa
Use Buchner flask and vacuum

30
Q

How do you compare a pure organic solid to an impure organic solid?

A

MP determination - compare to databook
Pure - high MP and low range
Impure - low MP & high range