Period 3 Flashcards
Na reaction with water
2Na + 2H2O = 2NaOH + H2
Alkaline solution as strong base fully dissociates
Reacts with cold water vigorously and fizzes gas of H2
Mg reaction with water (2)
Mg + 2H2O (l) = mg(OH)2 + H2
Reacts slowly as sparingly soluble in water
Mg + H2O(g) = MgO + H2
Forms white solid and bright light
Na with O2
Na + 1/2 O2 = NaO
Very fast
Orange flame and white ppt
Mg and O2
Mg + 1/2 O2 = MgO
Very fast
White flames and white ppt
Al with O2
2Al + 3/2 O2 = Al2O3
Slow but when powdered is fast
Sprinkle powder then you get bright light sparks
Si with O2
Si + O2 = SiO2
Slow
Orange flame
White solid
P4 and O2
P4 +5O2 = P4O10
Spontaneously combusts
White flames and white fumes
S + O2
S + O2 = SO2
High temperature and catalyst SO3 can be made
Steadily burns
Pale blue flames and colourless gas
Al2O3 as amphoteric
Base = 2NaOH + Al2O3 + H2O = 2NaAl(OH)4
Acid = 3H2SO4 + Al2O3 = Al2(SO4)3 + 3 H2O
Why does Al2O3 have a lower melting point than MgO
Al 3+ is smaller than Mg2+
More polarising than mg 2+
Distorts electron cloud around O2
More electron density shared between 2 ions
Bonding in NaO
Ionic
Bonding in MgO
Ionic
Bonding in Al2O3
Ionic
Binding in SiO2
Covelant. Macromolecular
Bonding in SO2
Covelant simple molecular
Bonding in P4O10
Covelant simple molecular
Acid base reaction
Forms salt and water
SO3 = H2SO4
SO2 = H2SO3
P4O10 = H3PO4
Test tube reaction for NaO and P4O10
React both with water
Measure PH
NaO should form a strong base
Describe method to determine melting point
Heat sample slowly in crucible
Until impurities are seen