Alkene Flashcards
C-C bond
Sigma bond
C=C bond
Pi and sigma
Why is there no rotation around a c=c bond ?
The pi bond formed by overlap of p orbitals
C=c are made from pi and sigma bond
If there was any rotation p orbitals would no longer overlap and the pi bond would break
Electrophile
Electron pair acceptor
Nucleophile
Electron pair donor
3 types of electrophiles
Halogen hallides eg Hbr
Halogens eg Br2
Sulphuric acid ( H2SO4)
How to tell if molecule is major or minor
Molecule made from tertiary carbocation which is more stable than secondary/ primary carbocation due to greater positive inductive effect as greater alkyl groups
Explain why bromine molecules react with the double bond in Alkenes
Bromine is a non polar molecule
The c=c has a high electron density/ is electron rich
This indices a dipole in bromine
The delta + is attracted to c=c double bond
Stereoisomers
Same structure formula but different arrangement of atoms in space
No rotation around c=c bond
Each carbon of the bond has two different group
E stereoisomers
Priority groups attach a different sides of carbon
Z. Stereoisomers.
Prior to group attached to same carbon on both sides