Oxidation and reduction Flashcards

1
Q

What were reactions that involved the addition of oxygen to a substance described as before the discovery if electrons?

A

Oxidation reactions

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2
Q

What was removing oxygen from a substance (before the discovery of electrons)

A

A reduction reaction as the mass of the substance got smaller due to the oxygen being removed.

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3
Q

What did scientists notice after the discovery of the electron?

A

That many chemical reactions involved the transfer of electrons.

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4
Q

What is meant by many chemical reactions involved the transfer of electrons

A

One substance lost electrons while another gained electrons.

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5
Q

Define oxidation

A

Occurs when the element loses electrons.

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6
Q

Define reduction

A

Occurs when the element gains electrons.

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7
Q

What is a useful way of remembering oxidation and reduction?

A

OIL RIG - oxidation is loss, reduction is gain.

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8
Q

Do oxidation and reduction occur at the same time?

A

Yes.

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9
Q

What is the name of the reaction that occurs when one element loses electrons and another element gains electrons?

A

Redox reactions.

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10
Q

Mg + O –>

A

Mg(2+) + O (2-) (Mg loses 2e, O gains 2e)

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11
Q

Zn + Cu (2+) –>

A

Zn (2+) + Cu
Zn is being oxidised = reducing agent
Cu is being reduced = oxidising agent

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12
Q

What is the element that loses the electrons called?

A

The reducing agent

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13
Q

What is the element that gains electrons called?

A

The oxidising agent

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14
Q

In the following equation pick out the species being oxidised, the species being reduced, the oxidising agent and the reducing agent = Fe(2+) + Cl –> Fe(3+) + Cl(-)

A
Fe = oxidised
Cl = reduced
Fe = the reducing agent
Cl = the oxidising agent
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15
Q

What side are the species being oxidised/reduced and the oxidising/reducing agent always on and why?

A
  • Left

- As they are reactants

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16
Q

What is a more useful way of keeping track of the movement of electrons?

A

By using oxidation numbers

17
Q

Define oxidation number

A

The charge an element has or appears to have when it is in a compound when certain rule are applied

18
Q

What type of bonding do we have to pretend that all compounds have in order to use oxidation numbers?(even thought its not true)

A

Ionic bonding

19
Q

What is done for the purpose of pretending that all compounds are ionic?

A
  • The less electronegative element becomes positive (loses electrons)
  • The more electronegative element becomes negative (gains electrons)
20
Q

What is rule 1 for oxidation numbers?

A

Simple elements i.e those that are not with any other elements, have an oxidation number of zero. (eg Na, Mg & Fe)

21
Q

What is rule 2 of oxidation numbers?

A

In the combined state, Group 1 elements always have an oxidation number of +1 and Group 2 elements always have an oxidation number of +2.

22
Q

What is rule 3 of oxidation numbers?

A

In simple ions i.e single elements ions, the oxidation number of the ion is equal to the charge on the ion.

23
Q

What is rule 4 of oxidation numbers?

A

The halogens, (Group 7) in compounds where the halogen is bonded to one other element, has an oxidation number of -1, unless the halogen is bonded to a more electronegative element, then the oxidation number of the halogen will be +1. ( doesn’t work for halogens in complex ions)

24
Q

What is rule 5 of oxidation numbers?

A

Oxygen usually has an oxidation number of -2: except in the compound OF2 it is +2 as F is more electronegative element than O and in the peroxide ion [O2 2-] where O has an oxidation number of -1.

25
Q

What is rule 6 of oxidation numbers?

A

Hydrogen has an oxidation number of +1 in its compounds : except when it is combined to an element less electronegative than it because then it is a hydride and has an oxidation number of -1.

26
Q

What is rule 7 of oxidation numbers?

A

In complex ions i.e where more than one element is in the ion, the oxidation numbers must add up to the charge on the ion.

27
Q

What is rule 8 of oxidation numbers?

A

In neutral molecules the oxidation numbers must add up to zero.

28
Q

Oxidation (in terms of oxidation numbers)

A

Oxidation is an increase in oxidation number.

29
Q

Reduction ( in terms of oxidation)

A

Reduction is a decrease in oxidation number