ESTIMATION OF THE TOTAL HARDNESS IN A WATER SAMPLE USING EDTA Flashcards

1
Q

what do you titrate water against to find the hardness

A

EDTA

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2
Q

what does EDTA stand for

A

ethylenediaminetetraacetic acid

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3
Q

what do you use during the titration

A

the disodium salt of the acid

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4
Q

how do you represent the disodium salt of the acid

A

Na2H2X

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5
Q

formula for experiemny

A

Na2H2X + Ca2+ -> CaH2X + 2Na+

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6
Q

indicator for the titration 2

A

eriochrome black or solochrome black

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7
Q

what does eriochrome black look like

A

a black powder

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8
Q

eriochrome black in hard water

A

wine/red

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9
Q

eriochrome black in non-hard water

A

blue

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10
Q

end point colour change

A

wine/red to blue

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11
Q

as the end point is difficult to detect, what must be done

A

must be carried out at a particular pH

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12
Q

how do you carry it out at the right pH?

A

use pH buffer 10

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13
Q

where is EDTA stored and why?

A

in a plastic containing as it has the ability to extract metal ions from glass if left in a glass container for too long

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14
Q

to make it easier, what do we attribute all hardness to?

A

CaCO3

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15
Q

first step

A

burette is washed out with deionised water and then some of the EDTA solution to prevent dilution

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16
Q

after burette cleaned

A

burette filled using a funnel (usual precautions)

17
Q

after burette filled

A

clamped vertically

18
Q

after burette ready

A

pipette washed with deionised water and then with water sample to prevent dilution of the sample

19
Q

pipette washed `

A

25 cm cubed of hard water sample pipetted into conical flask by touching tip off the inside of the conical flask

20
Q

water sample in conical flask

A

added 1cm cubed of buffer solution 10

21
Q

buffer solution in flask

A

pinch of Erichrome black added into conical flask also

22
Q

what colour is solution in conical flask when ready

A

wine/red

23
Q

burette and conical flask ready

A

carry out titration until end point