organic synthesis Flashcards

1
Q

alkene > alkane

A

-H2 (r)
-Ni catalyst (c)
-electrophilic addition

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

alkane > haloalkane

A

-X2 (r)
-uv light (c)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

alkene > haloalkane

A
  • H-X
    -Nucleophilic sub
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

haloalkane > nitrile

A

-NaCN in ethanol (R)
-heat under reflux (c)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

haloalkane > amine

A

-conc NH3 in ethanol (r)
-heat (c)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Nitrile > amine

A

-H2/Ni

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

haloalkane > 1 alcohol

A
  • NaOH aq (r)
    -reflux (c)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

2 alcohol > haloalkane

A

-H2SO4 (r)
- Na-X (r)
- sodium halide/H2SO4

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

alkene > alcohol

A

-steam H2O/ H3PO4

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

alcohol > alkene

A

-H3PO4
-or H2SO4 heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

alcohol > ester

A

-carboxylic acid
-conc H2SO4 or acid anhydride

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

aldehyde > 1 alcohol

A

-NaBH4

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

1 alcohol > aldehyde

A

-K2Cr7O7/H2SO4
-distillation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

1 alcohol > carboxylic acid

A

-K2Cr7O7/H2SO4
-reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

2 alcohol > ketone

A

-K2CR7O7/H2SO4
-Reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

ketone > 2 alcohol

A

-NaBH4

17
Q

Ketone > hydroxynitrile

A

-NaCN (aq) / H+ (aq)

18
Q

hydroxynitrile > amine

A

-H2/Ni

19
Q

aldehyde > hydroxynitrile

A

-NaCN (aq) / H+ (aq)

20
Q

aldehyde > carboxylic acid

A

-K2Cr2O7/H2S4
-Reflux

21
Q

carboxylic acid > ester

A

-alcohol/conc H2SO4

22
Q

ester > carboxylic acid

A

-dilute acid
-heat

23
Q

nitrile > carboxylic acid

A

-H2O/HCL
-heat

24
Q

carboxylic acid > acyl chloride

A

-SOCl2

25
Q

acyl chloride > carboxylic acid

A

-H2O

26
Q

acyl chloride > ester

A

-alcohol

27
Q

ester > carboxylate

A
  • OH-
    -heat
28
Q

acyl chloride > 1 amide

A

-NH3

29
Q

acyl chloride > 2 amide

A

-1 amine