Optical isomerism Flashcards

1
Q

What does chiral mean

A

Greek word for handedness

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2
Q

Chiral compounds are

A

Non super imposable
Mirror images
Enantiomers
Form of stereoisomerism
Can be a. C atom with 4 different groups - Chiral Centre (Most common form)

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3
Q

What does non superimposable mean

A

The enantiomers are mirrored and cannot be directly overlayedl

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4
Q

What is an enatiomer

A

Mirrored versions of the same chiral compound

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5
Q

What is a racemic mixture

A

Mixture of both enantiomers

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6
Q

What does optically active mean

A

chiral

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7
Q

If a molecule has one chiral centre, how many optical isomers will there be?

A

2

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8
Q

What is the difference between enantiomers of the same compound and how can the compound be identified?

A

Their ability to rotate plane polarised light, one rotates it clockwise and the other anticlockwise, compound can be determined by angle of rotation

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9
Q

Why cam polarised light not be used in a racemic mixture?

A

Enantiomers will rotate plane polarised light both clockwise and anticlockwise, keeping the angle at 0

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10
Q

What type of mechanism typically forms a racemic mixture?

A

Nucleophilic addition

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