A2- Acids and Bases Flashcards

1
Q

What is a buffer?

A

a substance that can resist the change in pH when a small amount of acid or alkali is added to it

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2
Q

What is a brønsted-lowry base?

A

a proton acceptor

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3
Q

What is a brønsted-lowry acid?

A

proton donor

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4
Q

What is a weak acid?

A

a proton donor that partially dissociates in water

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5
Q

What is a strong acid?

A

a proton donor that fully dissociates in water

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6
Q

What is the equation for pH?

A

pH = -log[H+]

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7
Q

How do you make a buffer?

A

add sodium salt to weak acid

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8
Q

Why can weak acids only resist the change in pH when H+ is added for a short time?

A

as less A- initially,
as H+ is added, A- is used up to form HA in a non-reversible reaction
This is quickly used up, and pH will change

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9
Q

Why does adding sodium salts help acids to resist change in pH?

A

as increases number of A- ions

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10
Q

What makes a suitable indicator?

A

rapid colour change

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11
Q

How do you calculate the [H+] in sulfuric acid?

A

2 x [H2SO4]

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12
Q

What assumptions are made when calculating the pH of H2SO4?

A
  • fully dissociated ([H+] = [acid]
  • diprotic, so each H2SO4 dissociates into 2 x H+
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13
Q

Why is the pure water always neutral, regardless of pH?

A

[H+] = [OH-]

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14
Q

Write the equation for the reaction of a strong acid with water

A

HA + H2O –> H3O+ + A-

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15
Q

Write the equation for the reaction of a weak acid with water

A

HA + H2O <–> H3O+ + A-

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16
Q

Give the equation for the ionic product of water (Kw)

A

Kw = [H+] [OH-]

17
Q

How do you modify Kw, in order to calculate the pH of pure water?

A

Kw = [H+]^2

18
Q

How do you calculate pKa?

A

-log Ka

19
Q

How do you calculate Ka from pKa?

A

10^-pKa

20
Q

Write an expression for Ka?

A

[H+][OH-] / [HA]

21
Q

Write a modified Ka for doing buffer calculations?

A

Ka = [H+] x (salt / acid)