equilibria - p1,2,3 Flashcards
What is an Equilibrium mixture
Where the proportions of all components in a mixture remain constant
Dynamic equilibrium
Where the forwards and backwards reaction occur at the same rate
What is Le chatelier’s principle
f a system at equilibrium is disturbed, the equilibrium moves in the direction to reduce the disturbance
Changing concentration in equilibrium
Increasing the concentration of REACTANTS or decreasing concentration of PRODUCTS causes a shift to the RIGHT (forward)
Increasing concentration of the PRODUCTS or decreasing concentration of REACTANTS causes a shift to the LEFT (Backwards)
What information shows if a reaction is exothermic or endothermic?
Reactions at equilibrium are shown with a value for H for the forward direction
- H indicates forward reaction is exothermic (and therefore reverse is endothermic)
+ H icates forward reaction is endothermic (and therefore reverse is exothermic)
What happens to the position of an equilibrium if pressure is increased?
The equilibrium shifts to the side of the reaction with less number of gaseous moles
What happens to the position of an equilibrium if temperature is increased?
The equilibrium shift to the endothermic direction to reduce temperature
what happens to the position of an equilibrium if the concentration of a reactant is increased?
The equilibrium shifts to the products to remove the added reactants
How does the addition of a catalyst affect a reaction at
equilibrium?
Does not affect the position of equilibrium, but speeds up the rate at which equilibrium is achieved
Why does a catalyst not impact the yield?
increases the rate of forwards and reverse reactions equally
What factor affects the value of Kc ?
temp only