Molecules and colour Flashcards
What type of compounds absorb electromagnetic energy?
Organic Compounds
Why are most organic compounds colourless?
The wavelength of light absorbed lies outside the visible range on the electromagnetic spectrum.
HOMO
Highest occupied molecular orbital.
LUMO
Lowest unoccupied molecular orbital
What is higher HOMO or LUMO
LUMO
Conjugated system
Relatively large number of carbon atoms with multiple double bonds and benzene rings. The pi and sigma bonds must be alternating
Explanation of coloured organic compounds.
Large conjugated system causes smaller gap between HOMO and LUMO, hence the energy gap is equivalent to the energy of a colour in EM spectrum. This colour is absorbed by the compound and the complementary colour is observed.