Module 2 Flashcards
1 atm is equal equal to
760 mmHg, torr
Definition of gases
Made up of small atoms or molecules that are constant, random, in linear motion
-the distance of separation is very large
Boyles law
-use if constant temperature
P1V1=PfVf
Charles law
- use if Pressure is constant
Vi = Vf
— —
Ti Tf
Combined gas law
PiVi = PfVf
—— ——
Ti Tf
Avocados law
-use of temperature and pressure are constant
Vi = Vf
—- —-
ni nf
Standard temperature and pressure
T= 273K
P= 1 atm
V= 22.4L
R= 0.0821 L•atm/ mol• K
Ideal gas law
PV=nRt
Condensation
Energy + h20(l) —-> H2O (g)
Evaporation
H20(g) —-> H20(l) + energy
Dipole dipole interaction
Attractive forces between polar molecules
HCl <—> HCl
London dispersion forces
Electrons in continuous motion, a nonpolar molecule, having instantaneous dipole
-* weakest force*
Hydrogen bonding
Very strong, intermolecular attraction, causing higher than expected boiling points in melting points
Ex: h20, nh3
Electrolytes
Salutes that are soluble ionic compounds
Mass/volume percent
G of solute
—————- x 100
mL of solution
Mad/ mass percent
G of solute
—————- x100
G of solution
Morality
Mole of solute
M=. ———————
L of solution
Dilution equation
M1v1= M2V2
Involves molarity
Molality
Mole of solute
———————
Kg of solvent
Calculating osmolarity
O= i• M
Molarity x Coefficient of products
Calculating osmotic pressure
Pie=iMRT
Moles• M • 0.0821• 273
Calculating ions
Ion= molar mass of ion
———————————-
# of charges on ion
Calculating ion concentration
Eq/L = (eq/mol ion) • M
Exothermic reactions
A-B+ C-D—> A-D+ C-B + energy
Combustion
Endothermic reactions
Energy + A-B + C-D—> A-D+ C-B
Decomposition
Enthalpy
Delta H = 🔼H products -🔼H reactants
Exothermic: - kcal
Endothermic: + kcal
Specific heat
Q= ms• 🔼T• 1.00cal/g*C
Catalyst
As substance that increases the reaction rate
General equilibrium rxn
aA +bB<_—> cC + dD
[C]^c+ [D]^d
Keq: —————
[A]^a+. [B]^b
Equilibrium constant
2HI<—->. H2+ I2
HI= 0.54M
H2: 1.72M
I2: 1.72M
1.72•1.72/ 0.54= 10.1
Acid ls and bases
Acid: proton H+ donor
Base: proton H+ acceptor
Strong acids
HCI, HBr,
HNO3, H2SO4, CIO4
Strong acids
HCI, HBr,
HNO3, H2SO4, CIO4
Strong bases
NaOH, KOH, Ba(OH)2
Acid base dissociation
HX+Y<-> X- + HY+
Hydronium ion
Keq: [H3O+] [OH-]
= 1.0• 10^-14
Calculating pH
pH= -log[H30]
Calculating pH and molarity
1.0•10^-14 = H3O [OH]
Calculating ph and buffers
Ka= [H3O] [CH3COO-]\ [CH3COOH]