Mass Spectrometer And Spectrum Flashcards

1
Q

What is a mass spectrometer used to find ?

A

To find relative masses eg
Ar, mr and isotopic abundance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is the acronym and the four stages of using a mass spectrometer

A

VIAD

1) vaporisation
2)ionisation
3)acceleration
4)detection

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Explain vaporisation

A

The sample is turned into a gas vapour by an electric heater

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Explain ionisation

A

The gas vapour particles are then bombarded by HIGH ENEERGY electrons β€”> electrons knock off particles β€”> leaving positive ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Explain acceleration

A

The positive ions are accelerated by a electric field

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Explain detection

A

-time taken for positive ions to reach detector depends on mass and charge

-high charged/lighter ions take quicker.

-lower charged/ heavier ions take longer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What happens when a mass spectrometer is used ?

A

A mass spectrum graph is made

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is on the y and x axis of the graph?

A

Y axisβ€”> isotopic abundance of % isotopic abundance

Xβ€”> relative mass OR/and mass divided by charge

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

How do you find out the ar using a mass spectrum graph??

A

-Times the y axis value by the x axis value
-add the values together and divide by 100 or TOTAL of isotopic abundance

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

How do you find the% relative isotopic abundance when it’s not given??

A

-You get the value at the top of the peak
- diving by all the values (abundance)
-times by 100

How well did you know this?
1
Not at all
2
3
4
5
Perfectly