Mass Spectrometer And Spectrum Flashcards
What is a mass spectrometer used to find ?
To find relative masses eg
Ar, mr and isotopic abundance
What is the acronym and the four stages of using a mass spectrometer
VIAD
1) vaporisation
2)ionisation
3)acceleration
4)detection
Explain vaporisation
The sample is turned into a gas vapour by an electric heater
Explain ionisation
The gas vapour particles are then bombarded by HIGH ENEERGY electrons β> electrons knock off particles β> leaving positive ions
Explain acceleration
The positive ions are accelerated by a electric field
Explain detection
-time taken for positive ions to reach detector depends on mass and charge
-high charged/lighter ions take quicker.
-lower charged/ heavier ions take longer
What happens when a mass spectrometer is used ?
A mass spectrum graph is made
What is on the y and x axis of the graph?
Y axisβ> isotopic abundance of % isotopic abundance
Xβ> relative mass OR/and mass divided by charge
How do you find out the ar using a mass spectrum graph??
-Times the y axis value by the x axis value
-add the values together and divide by 100 or TOTAL of isotopic abundance
How do you find the% relative isotopic abundance when itβs not given??
-You get the value at the top of the peak
- diving by all the values (abundance)
-times by 100