Bonding and structure; covalent bonds Flashcards
what are molecules formed from
2 or more atoms that bond togther whic could be the same or different.
what is covalent bonding?
-sharing of electrons
-between NON-metals
-electrostatic forces of attraction between shared pair electrons and postive nucleus.
what else is there between the postitve nuclei in covalent bonding + state why?
repulsion due to two positive nucleisβ> to maintain covalent bondβ> balence forces with attraction and repulsion
what are the physical properties of SIMPLE molecular covalent substances + what are they the opposite of?
OPPOSITE TO THE PHYSICAL PROPERTIES OF IONIC BONDING
-low mp==>little energy to ovecome the intermolecular forces between moleculesβ> weak compared to covalent bonds
-do not conduct electricityβ>no charge carriers
-insolubleβ> the water molecules are attracted to each other rather than the molecular substance
how are the bonding electrons represented in covalent bonds?
they are drawn with their outer atomic orbitals overlapping
for diatomic molecules how do you distinguish if there is a single double or triple bond?
you do 8 - the group number
what is dative bonding?
-a type of covalent bond
-when an atom donates a pair of electrons to an atom or ion to form a bond
how many dative and covalent bonds are shared in carbon monoxide?
2 covalent bonds and one dative bond
what compounds are excepetions for the oct rule in covalent bonding?
boron trifluride AND sulfur hexafluride
what are some examples of giant covalent strcutures?
-graphite
-diamond
-silicon dioxide
what do giant covalent structures have?
a huge network of covalently bonded atoms (millions)
how many carbons is graphite bonded to?
3 carbons and one delocalised electron
does graphite have a high or low mp and why?
high mpβ>lots of strong covalent bonds within graphene
do the layers slide easily or not in graphite and why?
a
yes because of the weak intermolecular forces between the layers of graphene
does graphite conduct electricity and why?
yes due to the 4th electron being delocalised β> carries charge