Lipids: Triglycerides, Phospholipids, and Sterols Flashcards
Lipid family includes…
Triglycerides, Phospholipids, and Sterols
Lipids composed of three fatty acids attached to glycerol
Triglyceride
Explain the structure of a Fatty acid
A chain of carbon and hydrogen atoms with an acid group and a methyl group on each end
acid group in fatty acids
COOH
how many carbons are in the chains of the most occurring fatty acids
even number of carbons of up to 24 carbons in length
simplest 18-carbon fatty acid
Stearic acid
- long chain fatty acids
- medium chain fatty acids
- short-chain fatty acids
- 12 to 24 carbons
- 6 to 10 carbons
- less than 6 carbons
fatty acids that has all its hydrogen atoms and only has single bonds
saturated fatty acids
a double bond in a chain of carbon in fatty acids
point of unsaturation
fatty acids that are missing hydrogen and has double bonds
unsaturated fatty acids
example of a monounsaturated fatty acid and where to find it
Oleic acid
- olive oil and canola oil
two examples of poly unsaturated and where to find them
linoleic acid
- sunflower, safflower, corn, and soybean oils, walnut oil
linolenic acid
- soy bean and canola oils, flax seeds, and walnuts, fish oil
what creates triglycerides
condensation reaction
takes a hydrogen from the glycerol and an OH from the acid end of the fatty acid creating H2O
what affects the firmness of fats
- degree of unsaturation: unsaturated fats are liquid at room temperature. The more saturated or the less double bonds - the more solid.
- the length of carbon chain: the shorter the length of the carbon chain, the softer at room temperature
what, when exposed to, causes fatty acids to rot?
oxygen
what is the most susceptible type of fatty acid to oxygenation? what is the least?
- polyunsaturated is the most susceptible
- saturated is the least
where can you find saturated fats?
- coconut oil
- butter
- palm oil
- pork fat
- chicken fat
where can you find monounsaturated fats?
- olive oil
- peanut oil
- canola oil
where can you find Omega 6 (Linoleic acid)?
- safflower
- sunflower
- cornoil
- soybean oil
- walnut oil
- cotton seed oil
where can you find omega 3 (Linolenic acid)?
- Flaxseed oil
- fish oil
- canola oil
`How can manufacturers protect fat from oxygenation?
- sealing in airtight, non-metallic container
- add antioxidants to compete for oxygen
- Hydrogenation: saturating points of unsaturation
- What is it called when the hydrogen beside a double bound is on the same side?
- what is it called when the hydrogen atoms beside the double bond are on opposite sides?
- Cis-
- Trans-
Trans fatty acids
- behave more like saturated fats
- increases blood cholesterol and risk of heart disease
what makes up only 5%of lipids in the diet?
Phospholipids and Sterols
- what is the best known phospholipid?
- describe its structure
- Lecithin
- structure includes glycerol, two fatty acid chains, and choline on the third site
what is the commercial use for phospholipids?
-emulsifier: due to the hydrophobic fatty acid and the hydrophilic phosphate group
Where can phospholipids be found? where can lecithin?
- phospholipids are used in mayonnaise, salad dressings, and candybars
- lecithing are found in foods like eggs, liver, soybean, wheatgerm, and peanuts.