LIPIDS Flashcards
Lipid examples
triglycerides
phospholipids
glycolipids
cholestrol
what are molecular proportions in lipids
lots of carbons and hydrogen atoms
little oxygen atoms
macromolecules
a very large organic molecule
triglyceride structure
one glycerol molecule C3H5(OH)3
three fatty acid chains
glycerol
has 3 -C
has 3 -OH
has 5 -H
they are alcohols
fatty acids
have carboxyl group (-COOH)
acidic as carboxyl ionises to form H+
saturated
only carbon-carbon single bonds present
exist as solid as high bp
what bonds form between glycerol and fatty acid in triglycerides
ester bonds (-cooc)
unsaturated
c–c double bond present
so lower boiling point as double bond causes bend/kink in structure so weaker intermolecular forces between fatty acid chains
exist as liquid (e.g oil)
fuctions of triglycerides
- energy source as it can be broken down in resp to release enery and generate ATP
(produces more energy than sugar/carbs) - energy store as it is insoluble in water it can be stored in adipose cells under skin
- insulation as adipose tissue under skin trap heat in
- insulation of nerves as forms myelin sheath for faster electrical impulse transmittion
- bouyancy as lipids are less dense than water (oil floats on water)
- protects plants (waxy cover of plants)
phospholipids structure
1 glycerol
2 fatty acids
1 phosphate group
phospholipids in water
phosphate group has a negative charge so phospholipids are polar (attracted to water)
but the fatty acid tails are non polar (water repelant)
so phospholipids have a hydrophillic head but hydrophobic tail (amphipathic)
micelles
tiny balls with hydrophillic head outwards and hydrophobic tails inwards
why are phospholipids good membranes
phospholipids may be free to move around in their layer but they wont ever expose their tails to water so they have stability
selectively permeable so only small, non-polar substances can pass through
cholestrol structure
sterol (steroid alcohol)
where is cholestrol made
liver in animal
stigmasterol
cholesterol derivative in plants
steroid hormones (made from cholesterol)
- vit D
- oestrogen
- testosterone
are all hydrophobic and small so can pass through phospholipid bilayers
test for presence of lipids
mix sample and ethanol in one test tube
pour another test tube w only water
pour solution into test tube w water
cloudy white emulsion forms (+ result)
stays colourless (- result)