Lipids Flashcards

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1
Q

What is the molecular structure of glycerol

A

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2
Q

What is the molecular structure of a saturated fatty acid with 5 carbons

A

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3
Q

What is a feature of saturated fatty acids

A

They have only have single covalent bonds between carbons

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4
Q

What is the structure of a mono-unsaturated fatty acid with 5 carbons in its chain

A

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5
Q

What is a feature of a mono-unsaturated fatty acid

A

It only has one double covalent bond in its chain

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6
Q

What is the structure of a poly unsaturated fatty acid with two double covalent bonds and 5 carbons in its chain

A

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7
Q

What is a feature of a poly unsaturated fatty acid

A

It has more than one double covalent bond between carbon atoms

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8
Q

What do the double covalent bonds in poly unsaturated fatty acids mean

A

The double covalent bonds are rigid and cause the molecule to bend ( a kink in the chain).

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9
Q

As a result of these double covalent bonds in poly unsaturated fatty acids what does this mean

A

They can;t pack together as closely making poly unsaturated fatty acids liquid at room temperature.

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10
Q

What are lipids

A

Molecules containing carbon, hydrogen and oxygen and they are macromolecules that aren’t build from monomers.

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11
Q

What is a property of lipids

A

They are non-polar molecules as the electrons in the outer shell are evenly distributed creating no partially positive or negative zones.

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12
Q

What are triglycerides

A

Contain a molecule of glycerol bonded to 3 fatty acid molecules

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13
Q

How does the bonding in a triglyceride occur

A

A glycerol molecule has 3 hydroxyl groups that can react with the hydroxyl group in the carboxylic part of a fatty acid forming an ester bond. This process is called esterification. A molecule of water is also made, so it’s a condensation reaction. Two more fatty acids then react with two more fatty acids producing a triglyceride.

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14
Q

What happens during digestion of triglycerides

A

Lipase enzymes break down triglycerides releasing the glycerol and fatty acid molecules. this reaction requires 3 water molecules and is a hydrolysis reaction.

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15
Q

What are features of triglycerides

A

They are non polar molecules so are hydrophobic and don’t dissolve in water. Because triglycerides contain lots of carbon and hydrogen lots of energy can be released from them.

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16
Q

What are phospholipids

A

They are comprised of glycerol, two fatty acids and a molecule with a phosphate group

17
Q

What are the bonds between glycerol and the fatty acids as well as the phosphate group

A

They are all ester bonds

18
Q

In a phospholipid what is the hydrophilic and hydrophobic part

A

The tail (fatty acids) are hydrophobic repelling water.
The head (phosphate group) is hydrophilic and attracts water as it’s charged.

19
Q

What happens when phospholipids are put in water

A

the molecules position themselves so that the hydrophilic head groups interact with water molecules while the hydrophobic tails cluster away from the water molecules. So a phospholipid layer is formed.

20
Q

What do the properties of phospholipids allow

A

It allows for phospholipids to form membranes

21
Q

What are sterols

A

They are steroid alcohols
They are complex with a 4 ring structure and an OH at one end
The OH is polar (hydrophilic), the rest is non polar (hydrophobic)

22
Q

What is cholesterol

A

Cholesterol is a sterol so has a hydrophilic OH group and the rest of the molecule is hydrophobic.

23
Q

What do the hydrophilic and phobic properties allow cholesterol to do

A

It allows cholesterol to insert themselves into cell membranes as the OH group interacts with the head of phospholipids and the rest with the tails

24
Q

Where is cholesterol most commonly made

A

It’s most commonly made in the liver and also intestines

25
Q

What is the purpose of cholesterol (1)

A

It’s a common part of membranes, regulating fluidity and is positioned between phospholipids - keeps membranes fluid at low temperatures, and stops them for becoming too fluid at high temperatures

26
Q

What is the purpose of cholesterol (2)

A

It makes up vitamin D, which is produced by the skin in response to U.V light and strengthens bones

27
Q

What is the purpose of cholesterol (3)

A

It makes up steroid hormones (e.g oestrogen and testosterone)

28
Q

What is the purpose of cholesterol (4)

A

It makes up bile which increases the rate of digestion of lipids by lipase.

29
Q

What are the roles of lipids (1)

A

Membrane formation and creation of hydrophobic barriers
Hormone production
Electrical insulation necessary for impulse transmission
Water proofing for example bird feathers

30
Q

What are the roles of lipids (2)

A

Thermal insulation to reduce heat loss
Cushioning to protect vital organs such as the heart and kidneys
Buoyancy for aquatic animals such as whales
They also have an important role in long term energy storage.

31
Q

What is the test for lipids

A

The emulsion test

32
Q

What are the steps for the emulsion test

A

First the sample is mixed with ethanol, the resulting solution is then mixed with water and shaken. if a white emulsion forms a layer on top then a lipid is present.