Intermolecular Forces Flashcards
__________________ forces are forces of attraction between molecules
Intermolecular
The forces of attraction between a ion and a polar molecule
Ion-dipole
Some ionic compounds do not __________ in water
Dissolve
If the ionic bond is __________ than ion-dipole attractions, the compound will not be soluble
Stronger
The attractive forces between the negative end of one polar molecule and the positive end of another
Dipole-dipole
Occurs between a Hydrogen that is covalently bonded to Flourine, Oxygen, Or Nitrogen and another F, O, or N with at least one lone pair
F, O, or N
Molecules with hydrogen bonds have a ____________ boiling point
Higher
The stronger the bond the ____________ the potential energy
Lower
In which the positive end of a polar molecule attracts the negative end of a non polar species and polarizes it
Dipole-induced Dipole
The strength of dipole-induced dipole forces also increases when the non-polar molecule is ________ and more polarizable
Larger
- forces that exist between all species
- the only intermolecular forces that keep assemblages of non polar species together
- caused by Coulumbic interactions between temporarily induced dipoles of neighboring species
induced dipole-induced dipole, aka London dispersion forces
Larger species with more electrons are more ____________
Polarizable
The presence of pi bonds ___________ polarizability
Increases
Why are heat of fusion values always positive
Melting is an endothermic process
When molecules leave the surface of a liquid to enter the gas phase, they exert a _________
Pressure
Vapor pressure increases as temperature ____________
Increases
Vapor pressure and rate of evaporation are higher in substances with _________ intermolecular forces
Weaker
When does a liquid boil?
When it’s vapor pressure equals the atmospheric pressure
The boiling point decreases as the elevation _________
Increases
Solids with high vapor pressured have relatively weak intermolecular forces, this can lead to _____________
Sublimation
Ionic compounds have a very ______ vapor pressure
Low
The resistance of a liquid to spread our and increase its surface area
Surface tension
Liquids with stronger intermolecular forces have __________ surface tensions
Greater
Intermolecular attractions between the liquid and the gas
Adhesive forces