Integrated Rate Laws (17.4) Flashcards
- Explain the form and function of an integrated rate law. - Perform integrated rate law calculations for zero-. first-, and second-order reactions. - Define half-life and carry out related calculations. - Identify the order of a reaction from concentration/time data.
What is the difference between rate laws and integrated rate laws?
- Rate laws describe how the concentrations of reactants change over time, providing equations that relate concentration to time.
- Integrated rate laws describe how the concentrations of reactants change over time, providing equations that related concentration to time.
What is integrated rate laws?
Equations that show how reactant concentrations change over time.
First-Order Integrated Rate Law
ln [A]= − kt + ln [A(initial)]
- Describes a reaction where the rate depends on the concentration of one reactant to the first power.
Second-Order Integrated Rate Law
Describes a reaction where the rate depends on the concentration of one reactant to the second power or two reactants to the first power.
Zero-Order Integrated Rate Law
Describes a reaction where the rate is constant and independent of the concentration of the reactant.
Half-Life
The time it takes for half of a reactant to be consumed in the reaction.