Identifying Anions(Complete) Flashcards

1
Q

What is an anion?

A

An ion with a negative charge and is attracted to the opposite charge of the anode- positive.

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2
Q

What charge are anions attracted to?

A

Attracted to the opposite charge of the anode-positive.

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3
Q

What anions do you need to know the tests for?

A
Chloride- Cl-
Sulphate- SO4
Sulphite- SO3
Nitrates- NO3
Carbonates- CO3
Hydrogen carbonates- HCO3
Phosphates- PO4
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4
Q

Describe the test for chloride ions.

Include the proof.

A

Add silver nitrate (AgNO3) solution.
A white precipitate of AgCl is formed.
Ag+ + Cl- = AgCl

Proof:
Add ammonia solution to the precipitate.
It redissolves,

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5
Q

Describe the test for nitrate ions.

Include the proof.

A
Dissolve in deionised water.
Add iron II sulphate solution- FeSO4.
Tilt the test tube at an angle.
Add concentrated sulphuric acid down the side of the test-tube.
A brown ring will form on the interface.
This is called the brown ring test.
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6
Q

What is the test for nitrate ions called?

A

The brown ring test.

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7
Q

Describe the test for sulphate ions.

Include the proof.

A

Dissolve in deionised water.
Add barium chloride solution- BaCl2.
A white precipitate of barium sulphate solution is formed.
Ba2+ + SO4 2- = BaSO4

Proof:
Add dilute hydrochloric acid to precipitate.
It does not redissolve.

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8
Q

Describe the test for sulphite ions.

Include the proof.

A

Dissolve in deionised water.
Add barium chloride solution- BaCl2.
A white precipitate of barium sulphite is formed.
Ba2+ + SO3 = BaSO3.

Proof:
Add dilute hydrochloric acid.
The precipitate redissolves.
BaSO3 + 2HCL = BaCl2 + SO2 + H2O

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9
Q

Describe the test for carbonate ions.

Include the proof.

A

Add hydrochloric acid solution.
CO2 is produced.
CaCO3 + 2HCL = CaCl2 + CO2 + H2O
If soluble the salt is potassium or sodium.

Proof:
Dissolve in water.
Add magnesium sulphate MgSO4 solution.
A white precipitate of MgCO3 is formed.
Mg2+ + CO3 2- = MgCO3.
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10
Q

Describe the test for hydrogen carbonate ions.

Include the proof.

A

Add hydrochloric acid solution.
CO2 is produced.
Ca(HCO3)2 + 2HCL = CaCl2 + 2CO2 + 2H2O

Proof:
Dissolve fresh sample in water.
Add magnesium sulphate solution- MgSO4.
No precipitate forms.

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11
Q

Describe the test for phosphate ions.

Include the proof.

A

Add concentrated nitric acid to some ammonium molybdate solution.
Add the mixture to the phosphate.
Heat gently using a water bath.
A yellow precipitate will form indicating the presence of a phosphate ion.

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