Hydrogen Flashcards

1
Q

% of hydrogen in the universe?

A

70

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2
Q

% of H in the atmosphere? % of H on Earth?

A

0.15, 15.4

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3
Q

What did Harold C. Urey win a Nobel Prize for? What year?

A

In the year 1934, an American scientist, Harold C. Urey, got Nobel Prize for separating hydrogen isotope of mass number 2 by physical methods.

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4
Q

% of deuterium? Half life of tritium?

A

0.0156, 12.33 years

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5
Q

Internuclear distance of H and D?

A

The same

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6
Q

High purity H2 is produced by?

A

Electrolyzing warm aqueous Ba(OH)2 with nickel electrodes

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7
Q

Water gas/ syngas is?

A

CO + H2

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8
Q

How is CO2 removed in water gas shift reaction?

A

sodium arsenite

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9
Q

Which bond has the highest for a single bond between two atoms of any element?

A

H-H

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10
Q

0.081% of H2 is dissociated at _____K and 95.5% of H2 dissociates at _____K

A

2000K, 5000K

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11
Q

CO + H2 ——-> CH3OH. What’s the catalyst?

A

Cobalt

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12
Q

Metallic hydrides electric conductivity?

A

Not as good as the parent metals

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13
Q

Lattices of which elements maintain same lattice when forming hydrides?

A

Ni, Pd, Ce, Ac

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14
Q

Does PH5 exist?

A

NO

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15
Q

What’s higher for H2O than D2O

A

Dielectric constant

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16
Q

Angle and bond length of water?

A

104.5 degree, 95.7pm

17
Q

When do ice form cubic lattice? Bond length?

A

low temperatures, 276pm

18
Q

Why does water have a high hydrating tendency?

A

Dielectric constant

19
Q

How many H-bonded water in CuSO4.5H2O

A

1

20
Q

Clark method uses?

A

Ca(OH)2

21
Q

Permanent hardness is caused by?

A

Chlorides and sulphates

22
Q

Calgon is?

A

Na6P6O18

23
Q

What is used in anion exchange method

A

Amine

24
Q

Three methods of production for H2O2?

A
  1. Acidifying BaO2 and removing water by evaporating (under reduced pressure)
  2. Peroxodisulphate hydrolysis (lab prep of D2O2)
  3. Industrially, auto-oxidation of 2-alkylanthraquinols
25
Q

Commercial h2o2 is?

A

10V

26
Q

Stabilizer for H2O2

A

Urea

27
Q

H2O2 is used to make

A

Hydroquinone, tartaric acid, cephalosporin

28
Q

H2O2 angles in gas phase? Solid phase?

A
  1. 8, 111.5 (laptop)

101. 9, 90.2 (laptop)

29
Q

H2O2 action in acidic medium?

A
  1. oxidation: +2

2. reduction: -2

30
Q

H2O2 action in basic medium

A
  1. oxidation: +2

2. reduction: -2