Gases Flashcards
Effusion
The rate at which a gas escapes through a pinhole into a vaccum (Through a small opening)
Gases are ideal under what conditions?
- High Temperature
- Low Pressure
Dalton’s law
Mixture of gas where each gas acts independently, the total pressure is the sum of the partial pressure
(Pt= P1 + P2 + P3 ….)
Avogardro’s Law
At constant temp & pressure volume is directly proportional to moles
Condition where gases are “Real”
- Low temp
- High Pressure
Charles Law
At constant pressure, volume & temp are directly proportional to each other (V1/V2 = T1/T2)
Presure of gas
Pgas = Atmospheric pressure + the difference in Hg level
Molar mass equation
MM= mRT/PV
Pressure of gas in open- ended manometer
Have to dtermine which side is lower where if the gas side is lower have to add the difference in Hg levels since the gas side is greater than atmospheric pressure (Visa Vers if its lower)
Combined gas law
P1V1/T1 = P2V2/T2
Average velocity
The velocity between Vmp & Vrms
(Vavg = square root(8RT/πMM)
Graham’s Law of effusion & diffusion
at constant temp & pressure, the rate that gasses diffuse & effuse is inversely proportional to the square root of their denisity or molar mass/weight
(R1/R2= suare root(M1) / square root(M2)
Density equation
MMP/RT
Manometer
a device used to mesure the pressure of a gas in a closed container
No name law
states that at consatnt temp & volume, pressure is directly proportional to the amount (moles) (P directly proportional to n)
Diffusion
is the rate at which two gages mix together (Gases move from high concentration to low concentration)
4 Variables that affect gas behavior
- Temperature
- Pressure
- Volume
- Amount
Gases
state of matter where particles are in constant, rapid, independent movement
Most probable velocity
Is the speed at which the largest number of particles are moving (Vmp = square root(3RT/MM)
The average kinetic energy is directly proportional to what?
Temperature
Boyle’s Law
At constant temp., pressure & volume are directly inversely proportional to each other (P1V1= P2V2)
Open-closed manometer
the side thats its open on depends on the atmospheric pressure
Avogadro’s Hypothesis
Equal volumes of different gas under the same conditions contains the sam enumber of particles
Kinetic energy
energy of motion like translational, vibrationalm, & rotational (its directly proportional to temp)
Van der Waals Equation
[P + an2/v2] (v-nb) = nRT
Gay - Lussac Law
At constant volume, pressure is directly proportional to temp (P1/P2 = T1/T2)
Pressure of gas in closed-ended manomteter
Since theres no exposure to the atmospheric pressure its depends on the difference in Hg levels
Ideal gas law
when nothing is constant PV=nRT (R= 0.0821 atm/mol)